We have designed and synthesized novel star shaped metal coordination compounds.
星型金属配合物材料的设计与合成。
Optical properties of a new type metal coordination complex nonlinear optical crystal zinc cadmium thiocyanate (ZCTC) are reported.
报道了新型金属络合物非线性光学材料ZCTC(硫氰酸锌镉)晶体的光学性质。
PAATEA gelator self-assembles into molecular gel by hydrogen bond, ionomer or metal coordination, which was proved by the FT-IR and theoretics analysis.
IR 及理论分析结果表明,该凝胶因子是通过氢键、离子聚集体或金属配位作用聚集、自我组装形成凝胶的。
The research on transition metal coordination polymers not only connects inorganic and organic chemistry but also involves basic theory and applications.
过渡金属配位聚合物的研究,不仅沟通了无机与有机化学的研究,而且集基础研究与应用研究于一体。
A series of bimetal coordination complex fibers with different content of metal were prepared by controlling the concentration of metal ions and reaction time.
通过控制金属离子的浓度和反应时间制得一系列不同金属含量的双金属配合物纤维。
At the same time, metal coordination polymers can be endowed with optics, electric and magnetism by selecting functional metal ions and organic ligands with functional groups.
同时,还可以通过选择功能性的中心金属离子和具有功能官能团的有机配体赋予目标金属配位聚合物以光、电、磁等功能。
The fourth section reports a series of new ligands and their many different metal functional coordination compounds as artificial nucleases were designed and synthesized by author.
第四部分是报导我们设计和合成了作为人工核酸酶的一系列新的配体以及许多不同金属的功能配合物;
The coordination compound formation mechanism of metal ion with NTO in alkali aqueous solution is discussed.
讨论了金属离子与NTO必需在碱性水中才能形成NTO的金属配合物机理。
Metal hydride compounds play a central role in coordination catalysis.
过渡金属氢化物在络合催化中占有重要的地位。
Self assembly of aryl group containing flexible bidentate ligands with metal ions gives rise to many types of novel structures because of their variable coordination modes.
芳基柔性二齿配体的配位构型多变,使得其金属配合物的结构丰富多彩。
The cyclodextrin and its derivative inclusion coordination can not only include with guest molecule, but also with transition metal complexes.
环糊精及其衍生物不仅能与简单客体分子包合,也能与过渡金属配合物进行包合的研究。
The departing halide extracts a proton from the second water and the generated hydroxyl ligand reacts with the ethylene, while remaining in the coordination sphere of the metal.
分开的卤化物从第二个水分子得到一个质子,同时产生的羟基配合体与乙烯反应,留在了金属的配位区内。
The coordination of azine with salts of transition metal were investigated and 10 new complexes were prepared.
研究了吖嗪化合物与过渡金属盐络合作用,得到了10个新吖嗪配合物。
The present paper covers the mechanism of coordination reaction of porphyrins with some metal ions studied by fluorometry and the catalytic mechanism of some catalysts.
本文用荧光光谱法初步研究了卟啉与金属离子配位反应机理和部分催化剂的催化机理。
When the concentration of the serum albumin was fixed and the ratio of metal ions to serum albumin increased, there exists similar configuration of the coordination center.
当增大金属离子与血清白蛋白的浓度比时,也发生类似的配位中心构型变化。
An organic coordination (complexing) compound in which the metal ion is bound to atoms of nonmetals, e. g. nitrogen, carbon, or oxygen, to form a heterocyclic ring having coordinate covalent bonds.
一种配位(络合)化合物,其中的金属离子与氮、碳或氧等非金属原子结合生成有配位共价键的杂环。
They are designed according to the special relations and coordination of metal-amino acid side chain in the active centre in known enzymes.
按照已有的酶活性中心的金属-氨基酸侧链配位和空间关系,设计合成多齿配体,并使配体和金属离子通过配位作用形成配合物。
The use of metal atoms in coordination polymers offers several possible advantages over purely organic chains, grids or frameworks which are organized by non-covalent interactions .
将金属原子运用于配位聚合物里可能会有几个优点,即由非共价作用组装在一起的单一的有机链,网格或骨架。
The geometric configuration of ligand and the coordination tendency of metal cation should be considered when constructing the coordination polymers.
构筑配位聚合物时首先要考虑配体的几何构型和金属离子的配位倾向性。
Recently, people have synthesized a lot of metal-organic coordination polymers with novel topological structure by using N-heterocyclic carboxylic acid ligands.
近年来,人们利用含氧多羧酸配体构筑出大量具有新颖拓扑结构的金属-有机配位聚合物。
Recently, people have synthesized a lot of metal-organic coordination polymers with novel topological structure by using N-heterocyclic carboxylic acid ligands.
近年来,人们利用含氧多羧酸配体构筑出大量具有新颖拓扑结构的金属-有机配位聚合物。
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