Why can't we just calculate equilibrium constants based on what we've seen so far.
我们为什么不能，直接计算平衡常数？
Next time we'll talk about the temperature dependence and the pressure dependence of equilibrium constants.
下次我们会讨论平衡常数对温度,和压强的依赖关系。
If we can calculate the partition functions for molecules, and they undergo reactions and they're in equilibrium, we should be able to calculate the equilibrium constants.
如果我们能计算分子的配分函数，而分子反应处于平衡状态，我们应该能够计算出平衡常数。
The ionization-recombination equilibrium constants increase with temperature.
随体系温度的升高，电离—复合平衡常数增大。
Some parameters can be obtained from the fitting results, such as adsorption equilibrium constants of additives.
由拟合结果可得到一些参数值，如吸附平衡常数等。
The results indicated that the equilibrium constants are not sensitive to both solvents and reaction temperature.
结果表明，平衡常数对溶剂和反应温度都不敏感。
The adsorption equilibrium constants decreased with the temperature, while the diffusivity increased with temperature.
烃分子的吸附平衡常数随温度的升高而降低，而扩散系数随温度的升高而增大。
With the increase of temperature the adsorption equilibrium constants decrease while the effective diffusivity increases.
实验结果表明，有效扩散系数随温度升高而增大，吸咐平衡常数则正好相反。
Coordination Numbers and equilibrium constants of axial coordination reaction were measured by visible spectra techniques.
用紫外可见分光光度法确定了轴向配位反应体系的配位数和平衡常数。
The formation enthalpy, free enthalpy and entropy of the complex have been calculated by equilibrium constants at different temperatures.
根据不同温度下的平衡常数计算了络合物的生成焓、生成自由焓和熵。
Here the comparison between the adsorption equilibrium constants obtained with single parameter model and five parameter model has also been made.
文中还对单参数模型和五参数模型求取的吸附平衡常数作了比较。
Thermodynamic equilibrium constants of chemical reactions which involve gaseous phases condensed phases and complex phases are strictly deduced in terms of chemical potential.
利用化学势的概念，导出气相、液相和复相化学反应体系的热力学平衡常数表示式。
Adsorption equilibrium constant has thermodynamic properties. The integral adsorption heat can be acquired from the adsorption equilibrium constants at different temperatures.
吸附平衡常数具有热力学性质，从不同温度的吸附平衡常数可以得到积分吸附热。
The equilibrium constants of addition reaction of alcohol to tetrahedral complex of cobalt with organophosphorus monobasic acids in octane are established by spectrophotometry.
用光度法测算了醇与有机磷一元酸四面体钴配合物加合反应的平衡常数。
The former includes the calculation of reaction free enthalpy, equilibrium constants, maximum output, gaseous phase partial pressure and theoretical decomposition voltage of molten salt electrolysis.
前者包括反应自由焓、平衡常数、最大产量、气相分压以及熔盐电解理论分解电压的计算；
A thermodynamic analysis of synthesis process of DMC by oxidation carbonylation of methanol was carried out with the emphasis on calculations of equilibrium constants and conversions for the reaction.
对甲醇氧化羰基化合成DMC的过程进行了热力学分析。着重计算了合成反应的平衡常数和平衡转化率。
A thermodynamic analysis of synthesis process of DMC by oxidation carbonylation of methanol was carried out with the emphasis on calculations of equilibrium constants and conversions for the reaction.
对甲醇氧化羰基化合成DMC的过程进行了热力学分析。着重计算了合成反应的平衡常数和平衡转化率。
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