目的:改进芳香腈的合成方法。
芳香族二醛与羟胺盐酸盐在85%甲酸或冰醋酸中回流可制备相应的芳香族二腈。方法简便,产率高。
Aromatic dinitriles were prepared with excellent yields by refluxing the corresponding aromatic dialdehydes with hydroxylamine hydrochloride in 85% formic acid or glacial acetic acid.
当然,人们也观察到了通过芳香C—H键活化产生的芳基碳钯键与腈基的分子间反应。
In- termolecular reactions were observed with the C—Pd bond formed by the C—H activation of the aromatic ring and the nitrile group.
该酶对芳香族腈、脂肪族腈、饱和腈与不饱和腈均能作用,并具有较好的对映体选择性。
The enzyme could accept aromatic or aliphatic nitriles, unsaturated or unsaturated nitriles as substrates with high enantioselectivity.
首先,对雪里蕻腌菜卤汁的乙醚萃取浓缩液组分进行了鉴定,结果发现有机酸组分8个,醇类组分4个,腈类组分2个,酯类组分1个,芳香烃2个。
The constituents from pickle brine extracted with ethyl ether and identified by GC MS. In the result, 8 acids, 4 alcohol, 2 nitriles, 2benzines and 1 ester were identified.
首先,对雪里蕻腌菜卤汁的乙醚萃取浓缩液组分进行了鉴定,结果发现有机酸组分8个,醇类组分4个,腈类组分2个,酯类组分1个,芳香烃2个。
The constituents from pickle brine extracted with ethyl ether and identified by GC MS. In the result, 8 acids, 4 alcohol, 2 nitriles, 2benzines and 1 ester were identified.
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