采用量子化学MNDO法,计算了氟代甲酰胺和N—氟代甲酰胺的1,2—氢迁移异构化反应势能面上的反应路径。
The reaction pathways of 1,2-hydrogen migration isomerization on the potential energy face have been calculated by the quantum chemistry, MNDO method.
氟代甲酰胺的氢迁移势垒低于甲酰胺的氢迁移势垒。
The potential energy barriers of hydrogen migration of the N-fluoro-formamide are lower than that of formamide.
用氢酶如何催化代谢物上氢的氧化或质子的还原以及配合态液中氧化还原过程的电子迁移规律阐释了生物的氧化还原过程中的电催化反应机理。
The electricity-catalyze mechanism is explained by Hydrogenases how to catalyse the oxidation of hydrogen or to the reduction of protons of metabolism and the el.
因此,金刚石单晶体的生长看来既受到太高的碳氢超饱和度的影响,也受到少量原子态氢的影响,还受到生长物质表面迁移率减小的影响。
Thus the growth of diamond single crystals seems to be disturbed either by too high hydrocarbon supersaturation or by less atomic hydrogen or by a decreasing surface mobility of the growth species.
因此,金刚石单晶体的生长看来既受到太高的碳氢超饱和度的影响,也受到少量原子态氢的影响,还受到生长物质表面迁移率减小的影响。
Thus the growth of diamond single crystals seems to be disturbed either by too high hydrocarbon supersaturation or by less atomic hydrogen or by a decreasing surface mobility of the growth species.
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