Now, you know with constant volume, H now it's not going to be delta H that's U straightforward to measure, it's going to be dealt u, all right.

好，现在你们知道在体积恒定的条件下，我们得到的不是Δ,我们直接测量到的是Δ,好，但这基本上也是一样的。

麻省理工公开课 - 热力学与动力学课程节选

You just change volume to pressure and basically you're looking at enthalpy under a constant -- anything that's done at a constant volume path with energy, there's the same thing happening under constant pressure path for enthalpy.

可以看到这就是把体积换成了压强,一般我们都是在一种恒定状态下,考虑焓的，任何在恒容条件下,能伴随能量变化的东西，也在恒压条件下伴随焓同样地变化,所以你可以经常。

麻省理工公开课 - 热力学与动力学课程节选

There's our condition for equilibrium at constant temperature and pressure.

这就是我们在,恒定温度和压强下的平衡条件。

麻省理工公开课 - 热力学与动力学课程节选

Could be done, but easier is to just do the whole thing at constant volume, right, and just run the reaction that way and redo the calculation to be a constant volume rather than constant pressure calorimeter, right.

可以进行测量,但是如果在体积恒定的条件下,做这些会容易得多,还是这样进行反应,但是在等体而不是恒压条件下重新计算。

麻省理工公开课 - 热力学与动力学课程节选

Now, we can immediately see what du/dV at constant entropy is.

我们能够很容易看出,恒定熵的条件下du/dV的数值。

麻省理工公开课 - 热力学与动力学课程节选