• But at the same time, entropy is going to be favoring whichever side has higher entropy, has more disorder, and there's a balance that's achieved.

    但是同时熵的变化可能,支持反应向着具有更高熵更无序的方向进行,这就是最终达到的平衡。

    麻省理工公开课 - 热力学与动力学课程节选

  • So if we have a negative change in energy for any reaction as it's written, what that actually means is we're giving off energy as the reaction proceeds.

    如果我们像这里写的这样,在任何一个反应过后,得,到的能量变化为负值,这就意味着我们在这个过程中放出了能量。

    麻省理工公开课 - 化学原理课程节选

  • Hess' Law states that for any chemical reaction, the energy change is path independent.

    盖斯定律表明,对于任意化学反应,能量变化并非是路径依赖的。

    麻省理工公开课 - 固态化学导论课程节选

  • Energy may be favoring reaction in one direction, toward let's say products that have lower energy.

    能量上的变化可能支持反应,向着产物具有更低能量的方向进行。

    麻省理工公开课 - 热力学与动力学课程节选

  • Sometimes second messengers collect signals from a variety of different receptor systems, translate them into one kind of internal change, and the cell then just has to know about that one thing changing.

    第二信使分子能够收集,来自不同受体系统的信号,将它们转化为同一种细胞内在的变化,这样细胞就只需对一种变化作出反应

    耶鲁公开课 - 生物医学工程探索课程节选

  • And we haven't talked about reactions at all yet, so you don't need to worry about the specifics of that exactly, but just that if you have this negative change in energy, you have a more stable product than you do reactant.

    当然我们还没有开始讨论反应,所以你不用担心它的细节是怎么样的,你只需要知道,如果能量的变化是负值,那么你将得到一个比反应物更稳定的生成物。

    麻省理工公开课 - 化学原理课程节选

  • That is to say I can now reroute that sodium plus chlorine reaction and go a different way, but I still end up with the same change in energy.

    也就是说,我可以重新定义一种,钠与氯的反应途径,从另一种途径来实现反应,但是能量的变化过程相同。

    麻省理工公开课 - 固态化学导论课程节选

  • And if I do that then I can find out the change in enthalpy of this reaction. It's just going to be the heat of formation of these three moles of water, minus the heat of formation of the iron oxide. OK.

    我就能得到这个,反应的焓的变化,它就是三摩尔水,的生成热,减去氧化铁的,生成热,好。

    麻省理工公开课 - 热力学与动力学课程节选

  • So, we were talking, however, about energy in terms of electron affinity, so we can actually relate electron affinity to any reaction by saying if we have this reaction written as here where we're gaining an electron, we say that electron affinity is just equal to the negative of that change in energy.

    但是,我们现在讨论的能量,是电子亲和能,因,此我们可以将电子亲和能,与任何反应联系起来,只要我们将反应写成这种得到电子的形式,我们说电子亲和能就等于,反应前后能量变化的负值。

    麻省理工公开课 - 化学原理课程节选

  • And I can calculate what happens to G under those conditions.

    因为在化学反应中组分就是这样变化的,我能够计算在这些条件下G的变化

    麻省理工公开课 - 热力学与动力学课程节选

  • So what we'll end up with is boron plus, 1 s 2 2 s 2 1 s 2, 2 s 2, E and what we say is the delta energy or the change in energy as the same thing as saying the energy of the products minus the energy of our reactant here, that's how much energy we have to put into the system to eject an electron.

    所以结果应该是正一价的硼,电子排布为,我们说,Δ,也就是,E,的变化量,等于生成物的能量,减去反应物的能量,这就是我们从这个系统中,打出一个电子所需要的能量。

    麻省理工公开课 - 化学原理课程节选

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