And in this case, the tie-breaker goes to the molecule in which the negative charge is on the most electronegative atom.
而在这种情况下,我们需要进行“附加赛“,也就是看看分子中带有负的,形式电荷的原子是不是电负性最高的。
So why don't you tell me what the formal charge should be on the sulfur atom of thionyl chloride?
那么请大家来告诉我亚硫酰氯中,的硫原子应该有多少形式电荷?
We could also figure out the formal charges, and obviously the formal charges between these two atoms, they're going to be identical, we're only dealing with oxygen atoms here.
我们还可以把形式电荷算出来,显然这两个原子的形式电荷,应该是完全相同的,我们要处理的只有氧这一种原子。
So, if we want to figure out the formal charge on the carbon, we need to take the number of valence electrons, so that's 4. We need to subtract the lone pair, what number is that? It's 2.
如果我们想算出碳原子的形式电荷,我们需要将价电子的个数,也就是四,减去孤对电子的个数,它是多少?是二。
And what's important to keep in mind about formal charge is if we have a neutral atom, such as we did in thionyl chloride here, the sum of the individual formal charges on individual atoms within the molecule have to equal 0.
而关于形式电荷记住一点是很重要的,那就是如果我们有一个中性原子,比如亚硫酰氯,那么这个分子中的所有原子的,形式电荷之和应该等于零。
If we look at our last structure here where we have nitrogen the middle, we can also figure out all those formal charges, and in this case we have plus 1 on the nitrogen, we have minus 2 on the carbon, and then we end up with a 0 on the sulfur there.
如果我们来看看最后一个结构,在中间的原子是氮,我们同样可以计算出所有的形式电荷,而在这种情况下,氮为正一,碳为负二,而最后硫为零。
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