• One is a little bit higher and one is a little bit lower than they are in the atomic situation.

    一个有点高,一个有点低,相比他们是原子状态的情景而言。

    麻省理工公开课 - 固态化学导论课程节选

  • We talked about this reaction here where we had chloride ion in the gas phase plus sodium ion in the gas phase.

    我们在讨论这一个反应,我们有气相的氯原子,与气相的钠原子接触。

    麻省理工公开课 - 固态化学导论课程节选

  • We don't have to just stick with carbon, we can think about describing other types of atoms as well using this hybridization.

    我们不用局限于碳,我们可以考虑利用杂化轨道,描述其它类型的原子

    麻省理工公开课 - 化学原理课程节选

  • The other chain is facing in the other direction, the 3' carbon is up, the 5' carbon is down.

    对面的那条单链方向相反,3'位的碳原子向上,5'位的碳原子向下

    耶鲁公开课 - 生物医学工程探索课程节选

  • Eighty percent of atoms that are set up like that break down in the next 24 hours; 20 percent of them don't.

    我们设定未来二十四小时中,有百分之八十的原子会分裂,另外百分之二十的原子不会

    耶鲁公开课 - 死亡课程节选

  • OK, then it says draw a single bond from each surrounding atom to the central atom, and subtract two valence electrons.

    后将中心原子与其相邻原子之间,连上单键,然后减掉2个价电子。

    麻省理工公开课 - 固态化学导论课程节选

  • It turns out that the antibonding orbital is a little bit higher from the atomic orbital level than the bonding orbital is lower.

    这证明了,反键轨道,比原子轨道高,成键轨道比原子轨道第。

    麻省理工公开课 - 固态化学导论课程节选

  • When it breaks this bond, that chlorine atom, a free chlorine atom comes down and reacts, this is ozone, with the ozone in the upper atmosphere.

    当它打破这个化学键,氯原子,一个自由的氯原子下来,和在大气层的上方的臭氧反应,这就是臭氧,在大气上层有臭氧。

    麻省理工公开课 - 固态化学导论课程节选

  • There's absolutely no reason I couldn't have switched it around and said that instead the pi orbitals form between these atoms instead of those first atoms I showed.

    我完全没有理由,不能把它转过来,现在π键在这些原子间,而不是我开始展示的那些原子间。

    麻省理工公开课 - 化学原理课程节选

  • We already moved way forward and completely revolutionizing the understanding of an atom in that there's something in an atom - it's not the smallest thing there is.

    我们已经超前走了一步,完全改变我们对原子的看法:,原子里面还有东西,它并不是最小的,但你也知道。

    麻省理工公开课 - 化学原理课程节选

  • Further, the nucleus is assumed to be the seat of the essential part of the mass of the atom, and to have linear dimensions exceedingly small compared with the linear dimensions of the whole atom."

    进一步的,核被认为是,原子主要质量所在的地方,和整个原子线性尺度相比,核具有很好的线性尺度“

    麻省理工公开课 - 固态化学导论课程节选

  • They take an atom of lead, accelerate it and have it collide with an atom of nickel.

    他们选取一个铅原子,将其加速,让它与镍的原子碰撞。

    麻省理工公开课 - 固态化学导论课程节选

  • That is why this says atomic number, but for most intents and purposes we can say this could be atomic mass.

    那就是为什么这里说原子序数,但如果没有意图和目的,我们就说是原子质量。

    麻省理工公开课 - 固态化学导论课程节选

  • So, selenium 2 minus is what's going to be isoelectronic, because if you add two electrons to selenium, you'll get the same electron configuration that you have for krypton here.

    负二价的硒离子将是等电子的,因为如果你给硒原子加上两个电子,你会得到,和氪原子相同的电子排布。

    麻省理工公开课 - 化学原理课程节选

  • He saw that if you take the atomic mass of chlorine, 2 add it to the atomic mass of iodine, divide by two, you get something that is really close to the atomic mass of bromine.

    他看到,如果你将氯的原子质量,加上碘的原子质量,除以,得到的数将与,溴的原子质量很接近。

    麻省理工公开课 - 固态化学导论课程节选

  • And what we've been talking about with all of these properties are, of course, how can we figure out what that is for a certain atom by looking at the periodic table, so we want to think about the periodic trend for atomic radius.

    对于我们讲过的这些性质,我们所讨论的一直都是,当然是,我们如何能够判断某一个原子的这些性质,通过观察周期表,因此我们需要思考一下原子半径的周期性规律。

    麻省理工公开课 - 化学原理课程节选

  • I'm an organic chemist, so I love carbon, it's one of my favorite atoms to talk about, but it would be nice to get to the point of bonding and even reactions to talk about all the exciting things we can think about once we're at that point.

    我是个有机化学家,我喜欢碳原子,这是我最喜欢谈论的原子之一,但我更喜欢讲成键,甚至化学反应的概念,一旦到了这之后,我们就可以考虑各种激动人心的事情。

    麻省理工公开课 - 化学原理课程节选

  • Here is the atomic nitrogen, here is the atomic nitrogen and these are the orbitals of molecular nitrogen.

    这是氮原子,这是氮原子,然后这是氮气的分子轨道。

    麻省理工公开课 - 固态化学导论课程节选

  • I said what hold the bonds together, what holds two atoms together is the attractive force we have between each electron and the other nucleus.

    我说过什么将它们结合在一起,将两个原子结合在一起的是一个吸引力,其中一个原子中的电子与另一个原子中的原子核之间。

    麻省理工公开课 - 化学原理课程节选

  • Can we explain why the ones that do break down break down and the ones that don't break down don't break down?

    我们能解释,为什么那个分裂了的原子分裂了,而没分裂的原子没有分裂吗

    耶鲁公开课 - 死亡课程节选

  • So where we had left off with was we'd fully discussed up to the point of considering homonuclear diatomic molecules, so molecules that both have the same nucleus.

    我们上次,讲到了我们,已经讨论过同核双原子分子,也就是有相同原子和的分子。

    麻省理工公开课 - 化学原理课程节选

  • So, that's actually the electron configuration we have when we're talking about copper and some other exceptions in the periodic table that you're going to be looking at.

    因此,这才是铜原子真正的电子排布,而且我们在元素周期表中,会看到与铜原子类似的,其他例外的情况。

    麻省理工公开课 - 化学原理课程节选

  • We could also figure out the formal charges, and obviously the formal charges between these two atoms, they're going to be identical, we're only dealing with oxygen atoms here.

    我们还可以把形式电荷算出来,显然这两个原子的形式电荷,应该是完全相同的,我们要处理的只有氧这一种原子

    麻省理工公开课 - 化学原理课程节选

  • The reason is because the predominant force at this point is going to be the attraction that's being felt between the nuclei and the electrons in each of the atoms.

    这是因为这时候最主要的力,是吸引力,它来自于,其中一个原子的电子与另外一个原子原子核之间。

    麻省理工公开课 - 化学原理课程节选

  • So in terms of the first step of skeletal structure, this is actually going to be easier because we don't have a central atom, we just have carbon and nitrogen here.

    对于第一步画出骨架,其实比刚才更容易,因为我们没有一个中心原子,我们这里只有碳和氮两个原子

    麻省理工公开课 - 化学原理课程节选

  • In terms of where different atoms are in a molecule, if you have a hydrogen atom or a fluorine atom, you can pretty much guarantee they're always going to be terminal atoms.

    对于不同原子在分子中的位置,如果你有一个氢原子或者一个氟原子,那你基本可以保证,它们总是最末端的原子

    麻省理工公开课 - 化学原理课程节选

  • So you can think about how these 2 things combined are going to be electronegativity, which is a measure of how much an atom wants to pull electron density away from another atom.

    因此你可以想象出,这两样性质合起来就是电负性,也就是一个度量,关于一个原子,有多希望把另一个原子的电子密度拉过来的。

    麻省理工公开课 - 化学原理课程节选

  • So, we can put our sulfur in the middle, and then it doesn't really matter how we draw the rest of it, where we put our c l's versus where we put our oxygen.

    那么,我们可以把硫放在中间,然后把其它的原子画在哪里就不重要了,把两个氯原子与一个氧原子放在哪里都行。

    麻省理工公开课 - 化学原理课程节选

  • This should make sense, because if an atom has a very high electron affinity, that means it's really happy taking an electron from another atom, or taking a free electron -- that that's very favorable.

    这应该是合理的,因为如果一个原子有很高的电子亲和能,这意味着,它非常乐意从另外一个原子那里夺取一个电子,或者得到一个自由电子--这是非常利于发生的。

    麻省理工公开课 - 化学原理课程节选

  • When we talk about resonance structures, we're talking about cases that have the same arrangement of atoms the key is the atoms are the same, and the thing that is different is the arrangement of electrons here.

    当我们讨论共振结构的时候,我们讨论的是原子排布相同情况,关键在于原子是相同的,不一样的只是电子排布。

    麻省理工公开课 - 化学原理课程节选

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