He said that the percent ionic character, and this is within a bond, not for a compound, for a covalent bond.
他提到离子百分数,是指一根键中,并非一个分子中。
So we haven't gotten to molecules yet, we're just talking about single atoms or single ions, but what's nice is just talking about this very straightforward principle of atomic radius.
我们还没有开始讲分子,我们仍然只是在讨论单个原子或离子,但它的好处在于可以讨论,这个关于原子半径的非常简单直接的原理。
So, for example, just talking about hydrogen cyanide or the cyanide anion, these are both molecules which are used in organic synthesis, so particularly the cyanide anion and salts of the cyanide anion.
那么,比如,就拿氰化氢,或者氰离子来说,它们都是用于有机合成的分子,特别是氰离子和氰离子的盐。
And that's all that's big enough to pass through or small enough to pass through. And if we go up even just one row on the periodic table to potassium, what we actually see is now that it's going to be too large, and, in fact, a potassium solvated with one water molecule won't go through our channel.
就是这样刚好大到它通过,或者说刚好小到它通过,即使我们再沿着周期表往下走仅仅一行到钾离子,我们看到的就将是它的个头太大了,实际上,溶解于一个水分子的单个钾离子,不能穿过我们的通道。
So if you're trying to make a more complicated organic molecule carbon-carbon bonds are one of the most difficult things to make in organic chemistry, and it turns out that c n minus is a very reactive molecule, so it's a good way, even though we'll go over some drawbacks in a second, it is a good way to make carbon-carbon bonds.
如果你要合成一个更复杂的有机分子,碳碳键是有机化学中,最难制造的键之一,而实际上氰离子是一种具有很高活性的分子,用它是一个好办法,尽管我们一会儿将看到它的一些缺点,但它的确是一个制造碳碳键的好方法。
So that's going to be the end of the exam 1 material, and then we'll move on to exam 2 material, which is kind of exciting, because we've been talking about just individual atoms and ions up to this point, and now we can talk about molecules, so we're going to start talking about bonding.
到此为止就是第一次考试的内容,接下来我们会开始讲第二次考试的内容,这些内容令人有点兴奋,因为我们一直都只是在讨论单个的原子,和离子到目前为止,而现在我们可以讨论分子了,要开始讨论成键的问题了。
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