And in practical terms, we can define the efficiency as the ratio of the heat in to the work out.
在实际中,我们定义,效率为热与功的比值。
You calculate how much heat is released in the reaction. And then what's going to matter is what's the heat capacity of the whole, of the calorimeter?
就是计算在反应中,放出了多少热量,接下来关键的是,整个量热计的热容是多少?
Remember we were just demonstrating, listening to the Ravel Bolero.
刚才的热场过程中我们示范过的,我们欣赏了拉威尔的《波莱罗舞曲》
This one turns out to be the heat capacity, and this one turns out to be something that we measure in the Joule-free expansion.
其实,这就是热容,这是焦耳自由膨胀实验中,我们要测量的物理量。
so that's what we think we know in constant pressure calorimetry.
好,我想这就是我们,在恒压量热法中所知道的。
Right? In other words I've got the stoichiometric coefficients in there and the values, and I'm subtracting the reactants from products -1652kJ/mol wind up with minus 1652 kilojoules per mole.
对吧?换句话说这里我用了化学,计量系数和生成热的值,从生成物中减去反应物,最后得到。
Every time you do the experiment T in equilibrium with the heat bath at T, v2 you'll get the same p2 and V2.
与热库相接触的每次实验中,达到热平衡后的温度都是,压强都是p2,体积都是。
We have discovered that this partial derivative that appears in the definition, the abstract definition of the differential for internal energy, is just equal to the constant volume heat capacity.
我们还发现,这个偏微分出现在了,内能的偏微分,定义式中,它也就是热容。
You couldn't just run something successfully in a cycle and get work out of it, using the heat from the hot reservoir, without also converting some of the heat that came in to heat that would flow into a cold reservoir.
如果一样东西在循环工作过程中,只有热从高温热源中流出,而没有热流入低温热源,那么此过程,不可能对外做功,不可能把所有热。
Calorimeter doesn't change in this process.
量热计在这个过程中并没有改变。
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