• And something that we'll see later on is that triple bonds, for example, are going to be stronger than a corresponding double bond or a corresponding single bond.

    而我们以后还会看到三键,举例来说,应该更强,相较于相应的双,或者相应的单来说。

    麻省理工公开课 - 化学原理课程节选

  • so you can see that there is going to be two sets in antibonding, three sets in bonding for a net of one, giving us the single bond.

    因此你能看到,反轨道上有两组,组成,得到一组净成,所以成的是单

    麻省理工公开课 - 固态化学导论课程节选

  • Let's re-draw this, so it looks a little bit neater, where we have a triple bond in the middle instead, and again, we need our negative 1 charge there.

    让我们重写这个,这样看起来更整洁一点,我们有一个三键在中间,同样地,我们这里需要一个负电荷。

    麻省理工公开课 - 化学原理课程节选

  • So let's take the case of acetylene where we have two carbon atoms that are going to be triple bonded to each other, each are bonded to a carbon and then to one hydrogen.

    让我们来看一看乙炔的例子,我们有两个碳原子,成三键,每个碳和一个碳一个氢相连。

    麻省理工公开课 - 化学原理课程节选

  • So, for example, down here I wrote that it was n 2 and that it was h 2, but when I re-wrote the molecules up here, you saw that it's an h h single bond where it's a nitrogen-nitrogen triple bond.

    比如,在这下面我写的是氮分子2,而这个是氢分子,但我在上面把这些分子的形式改写了,大家可以看到,这是一个氢与氢之间的单,含一个氮与氮之间的三键

    麻省理工公开课 - 化学原理课程节选

  • So, if we talked about a nitrogen-nitrogen single versus double versus triple bond, the triple bond will be the shortest and it will be the strongest.

    因此,如果我们讨论的是氮与氮之间的单,双三键,那么三键应该是其中最短的一个,同时也是最强的一个。

    麻省理工公开课 - 化学原理课程节选

  • Is a hydrogen bond shorter, or is a nitrogen-nitrogen triple bond going to be shorter?

    是氢的更短,还是氮与氮的三键更短?

    麻省理工公开课 - 化学原理课程节选

  • And then we have a triple bond there because we have 3 pairs of electrons.

    然后那里还有一个三键,因为我们有对电子。

    麻省理工公开课 - 化学原理课程节选

  • When you are done you have three electron pairs in bonding orbitals.

    当你完成的时候,成轨道上共有对电子。

    麻省理工公开课 - 固态化学导论课程节选

  • This is very easy molecule because we know exactly where to put them without even having to think, we only have one option, and we'll make a triple bond between the carbon and the nitrogen.

    这个分子非常简单,因为我们知道应该把它们放在哪里,甚至不用去想,我们只有一个选择,我们将在碳与氮之间形成一个三键

    麻省理工公开课 - 化学原理课程节选

  • So, in general what we see, and this is always true if we're comparing the same atom, and in general, if we're comparing different types of molecules, but we know that a single bond is always weaker than a double bond, which is weaker than a triple bond.

    通常我们会看到,这对比较相同原子来说总是正确的,通常,如果我们要比较不同种类的分子,但我们知道单,总是要比双弱,双总是要比三键弱。

    麻省理工公开课 - 化学原理课程节选

  • So it looks a lot less messy if we just draw our Lewis structure like this for h c n, where we have h bonded to c triple bonded to n, and then a lone pair on the nitrogen there.

    这看起来整洁了不少,如果我们把氰化氢的路易斯结构画成这样的话,这样我们就有氢与碳之间的单和碳与氮之间三键,然后还有一对孤对电子在氮这里。

    麻省理工公开课 - 化学原理课程节选

  • So now let's think about a triple bond.

    现在我们来看看三键

    麻省理工公开课 - 化学原理课程节选

  • N 2 So any chemist should be able to just look at n 2 and know that it's a triple bond, but that's not something that we've learned how did to do yet, so let's go ahead and start a new topic that's going to allow us to have some sort of sense of what the valence electron configuration, which includes whether something's a single or double or a triple bond can be figured out for any given molecule.

    任何一个化学家都应该能够仅仅通过看到2,就知道它有一个三键,但是我们还没学习如何做到这点,因此下面我们就开始进入一个新的主题,它将使我们能够有一定的认识,对于价电子的排布情况,包括可以对任何一个给定分子中的是单,还是三键作出判断。

    麻省理工公开课 - 化学原理课程节选

  • So let's think about how we can classify single and double and triple bonds, which is what we're really used to dealing with in terms of these sigma bonds and these pi bonds.

    让我们想想怎么来分类单,和三键,这在我们在考虑sigma,和π是很有用的。

    麻省理工公开课 - 化学原理课程节选

  • A triple bond, again is going to have one sigma bond on the internuclear axis.

    一个三键,同样的也有沿着核间轴sigma

    麻省理工公开课 - 化学原理课程节选

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