• Remember this is our bond axis here, and you can see there is this area where the wave function is equal to zero all along that plane, that's a nodal plane.

    记住这是我们的键轴,你可以看到在这些区域,波函数在这个面内全都是零,这是节点面。

    麻省理工公开课 - 化学原理课程节选

  • So, the wave function at all of these points in this plane is equal to zero, so therefore, also the wave function squared is going to be equal to zero.

    因此这里的,波函数平方也等于零,如果我们说在这整个平面上,任何地方找到一个p电子的概率都是零。

    麻省理工公开课 - 化学原理课程节选

  • So, if we say that in this entire plane we have zero probability of finding a p electron anywhere in the plane, the plane goes directly through the nucleus in every case but a p orbital, so what we can also say is that there is zero probability of finding a p electron at the nucleus.

    而只要是p轨道,这个平面都直接,穿过原子核,那么我们,可以说在原子核上,找到一个p电子的概率为零。

    麻省理工公开课 - 化学原理课程节选

  • But in sigma orbitals, you have no nodal planes along the bond axis, so if we had a nodal plane here, we'd see an area where the wave function was equal to zero.

    但在sigma轨道里,沿着轴向是没有节点平面的,如果我们有个节点,我们就会看到某个地方波函数等于0。

    麻省理工公开课 - 化学原理课程节选

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