And so we can actually think about how do we calculate what the dissociation energy should be for h 2, so let's go ahead and do this.
因此,我们其实可以想到应该如何计算,氢分子的离解能,那么我们开始做一下吧。
What I want to point out also is that this h hat, the Hamiltonian operator written out for the simplest case we can even imagine, which is a hydrogen atom where we only have one electron that we're dealing with, and of course, one nucleus.
我也想指出的是,我们能想到的最简单情况,的哈密顿算符,是一个只有一个电子,也只有一个原子核的氢原子。
stdio c So somewhere there's standard IO dot C, stdio h somewhere they're standard IO dot H, but, for me, right now, the only file I need to know about is the dot H, -- because what Sharp include really does -- it's what's called a preprocessor directive.
所以某个地方有一个,现在对于我来说它们是,我只要知道那个,h文件,因为Sharp包含的-,叫做预处理指令。
All right, so now let's see how we execute it, and do the calculations that allow us to calculate this. So, one, what's delta H in step one?
好,现在我们看看怎样操作它,怎样进行计算,第一步,步骤I的ΔH是多少?
So, let's change our graph where we now have this zero point set as the two individuals hydrogen atoms, and then we see that our h 2 molecule is at the negative of the dissociation energy, or the negative what that bond strength is.
那么让我们把曲线图中的零点能改到,两个分离的氢原子处,那我们就会看到,氢分子就是负的离解能,或者负的键的强度。
So if you're working with cyanide in the lab as potassium cyanide or sodium cyanide, those are what are called p h s's, it's a rating for different kinds of chemicals.
因此如果你在实验室中,需要用到氰化物,比如氰化钾或者氰化钠,这就是所谓的,“P,H,S“,这是化学药品有害程度的一个级别。
I change the temperature, what does that mean?
只改变温度,偏H偏p是多少?
So what actually turns out the reality is that h e 2 does exist, but it exists as the weakest chemical bond known, and it wasn't, in fact, even found to exist until 1993, so I can assure you this is not a bond that you see very often in nature, and it is a very, very weak bond.
实际上He2键是存在的,但它是目前所知的最弱的键,直到1993年它才被发现,所以我可以向你们保证在,自然界你们不可能经常看到它,它是种非常非常弱得键。
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