But now it's going to make more sense because in that case we were just talking about single electron atoms, and now we're talking about a case where we actually can see shielding.
但是现在能讲得通了,因为在那个情况中我们仅仅是现在我们讨论的是,讨论单电子原子,看到屏蔽的案例,我们能看到屏蔽。
So what we'll have here is a trigonal planar case, and you can see that we only have three electrons that are set for bonding, so we'll add three hydrogens, and for b h 3, we'll get a stable structure here.
让电子劲量远离的时候,不用考虑它,这个例子是平面三角形,你可以看到,只有3个电子可以成键。
We're going to see an example of that in a second. What we really want to worry about, what's the worst case that happens.
我们接下来就来看一个这样的例子,我们要关注的是,发生的最坏情况是什么呢?
Now at the very bottom, should we see a default case.
现在在最下面,我们会看到一个default,分支。
So what we see is that structure a is the most stable because we have the least separation of charge in the case of structure a.
因此我们看到结构,A,应该是最稳定的,因为这种情况下,分开的电荷最少。
So, it turns out that in this case, 2 p and any time that we see we're going from a 2 s to 2 p, filling in of electrons, we actually see that little bit of glitch in ionization energy.
在这种情形下的结果就是,任何时候我们从,2,s,到,填充进电子,我们都会看到电离能会稍稍偏离我们的规律。
So we can think of a third case where we have the 3 s orbital, and in the 3 s orbital 0 we see something similar, we start high, we go through zero, where there will now be zero probability density, as we can see in the density plot graph.
第三个例子那就是,3s轨道,在3s轨道里,我们看到类似的现象,开始非常高,然后穿过,这里,概率密度是0,就像你们在概率密度图里看到一样,然后我们到负的。
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