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And then we calculate changes, the convention is understood with respect to what is the zero, right.
然后我们计算改变,这个约定就是用来规定零点的位置的。
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And an electron is something where, i n fact, we might be able to, if we calculate it and see how that works out, actually observe some of its wave-like properties.
如果我们对电子做计算,并且知道如何算出来的,那么我们是可以观测到,电子的一些波动性质的。
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Do we calculate, you know, delta S, delta u, delta H?
是否要计算熵的变化，内能的变化，自由焓的变化？
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And we can go through and calculate the value of this quantity in parenthesis. And, when we do so, we get the value 2.18 times 10 to the minus 18 joules.
我们能进行计算这些值,如果我们这样做，我们能算出是，2。18，乘以10，的负18焦耳。
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Without showing your neighbor what you're doing, put in the box below a whole number between 1 and a 100 We will calculate the average number chosen in the class.
从1到100之间选择一个号码填到,下面的方框内,不要让你同桌看到,我们会计算全班的平均数
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What it means is if you'd release a rock at that location one second before with a certain speed that we can calculate, it would've ended up here with precisely the position and velocity it had at the beginning of our experiment.
它的意义在于,若在该处以特定速度抛出一个物体,这个速度可通过计算得到,一秒之后,物体会运动至我们设定的起点,并且速度为我们设定的初速度
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And so we can actually think about how do we calculate what the dissociation energy should be for h 2, so let's go ahead and do this.
因此，我们其实可以想到应该如何计算,氢分子的离解能，那么我们开始做一下吧。
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Here is what we calculate to tell whether it happens spontaneously.
这就是我们所需要计算的物理量,它能够告诉我们变化是否会自发发生。
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So we're going to go through a thermodynamic cycle, and here's what I want to calculate when we do this.
那么我们要推导,一个热力学循环,这是这个过程中我要计算的东西。
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And we can calculate that with the formula that we used, which was just n minus l minus 1 equals the number of nodes.
这个我们可以用我们以前用过的那个公式来计算，也就是节点数等于ｎ减去ｌ减去１
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Which means that g we can really calculate all the thermodynamics in terms of only g.
这意味着,我们能够利用,计算出所有的热力学量。
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And, in fact, these are the only two types of nodes that we're going to be describing, so we can actually calculate both the total number of notes and the number of each type of node we should expect to see in any type of orbital.
事实上，我们只,描述这两种节点，所以我们可以,计算任何轨道中的,总结点数以及各种节点数。
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So we should be able to calculate a z effective for any atom that we want to talk about, as long as we know what that ionization energy is.
我们应该可以计算出任何一个,我们想要谈论的原子的有效电荷量，只要我们知道电离能是多少。
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All right. So let's test what we, in fact, know about the photoelectric effect, and before we do that actually, we're going to calculate what we would predict, so when we do the demo it will be meaningful and we can tell whether we're successful or not.
好的，我们来测试一些，我们实际上懂了,多少光电效应的东西，在我们做测试之前，我们先算一下我们能预知什么，这样我们做的测试会很有意义,并且也知道我们是否成功了。
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In fact, we're going to do some of that today, u OK, calculate delta u.
待会我们就来看看，怎样计算Δ
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And, we could easily calculate the energies.
我们就能很容易的算出能量。
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But let's say we wanted to calculate the energy.
言归正传，我们要计算他的能量。
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The purpose here is to look at a series of processes in which temperature is held constant, and we're going to calculate how much work we get from allowing a gas to expand under various conditions.
目的是让大家了解一下,几个保持温度不变的过程，然后我们将计算,气体在不同膨胀过程中,的对外做功。
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And we can calculate the ionization energy.
我们能够计算电离能。
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And just like we saw before for the case of entropy in an isolated system, now we have something we can calculate.
就像我们前面看到的,孤立系统的熵一样，现在我们有一些可以计算的东西。
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OK, so let's go through this and see what we would do which is to calculate the heat and the work. This is well insulated.
好的，让我们开始然后看看,我们该怎样计算热量和功的大小,这是完全绝热的，所以。
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This is going to be probably a homework at some point to do this. For now, let's take it for granted. Let's take it for granted that we know how to calculate this derivative from an equation of state like this.
这可能是将来的一个课后作业,现在，请把这当成理所当然的，理所当然地认为我们,知道怎样从一个状态,方程计算这样的微分式。
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Not one of these variables. And we can calculate that.
所有的这些变量都我们能够计算的。
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Now what I want to do is put up a specific example of the cycle that can be undertaken inside here in an engine, and we can just calculate from what you've already seen of thermodynamics.
现在我想做的是,举一个例子,来具体说明热机内部的循环过程，同时我们可以利用热力学定律进行计算,看看热力学参量发生了什么变化。
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But the other reason to go through the thermodynamic cycles and really to develop great facility with them is because there are just an awful lot of things in nature and things that we build that run in cycles, where we want to calculate the thermodynamics, right.
但是要推导热力学,循环并为之发展一套,完善方法的另外一个原因是,自然界中或人造的那些,我们想计算它们的热力学的东西,有很多是以循环的方式运作的。
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We can tabulate them. We can know them, and then when we have reactions that inter-convert different compounds, we can calculate the heat of reaction is just the difference between the heat of formation of the reactants, and the heat of formation of the products, right.
种化合物的生成热，可以把它们列成表,可以认知它们，而当我们要处理，在不同化合物间转变的反应时,我们只要计算反应物和,生成物的生成热之间的不同,就能计算出反应热。
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But because in many cases we can reasonably either model or measure equations of state, collect data for a material for its temperature, pressure, volume relations, then in fact if we can relate all these quantities to those then in fact we really can calculate essentially all of the thermodynamics. For the material.
但是因为在很多情况下,我们能够合理的给出状态方程的模型,或者通过收集一个物质的，温度，压强和体积之间的关系,来测量其状态方程，所以实际上我们可以给出压强等物理量,和热力学势之间的关系,并计算出所有的热力学势，对于给定的物质。
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We can measure the heat capacity at constant volume, and now we have another term, and if we can figure out how to measure it, we'll have a complete form for this differential du which will enable us to calculate du for any process.
我们能够测量恒定体积下的热容，这里我们有另一项，如果能够知道怎么测量它，问我们就有了这个完整的微分式,就能够对任何过程计算。
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OK, now what we'd like to do is be able to calculate any of these quantities in terms of temperature, pressure, volume properties.
现在我们想要做的是能够利用,温度，压强和体积的性质,计算上面的物理量。
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That is, in terms of equations of state. For any material Then we would really be able to essentially calculate anything. Anything thermodynamic.
换句话说，利用任何一种物质的状态方程,我们就能够实质上,计算所有物理量，所有热力学量。
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