• If these bonds were all completely of equal distance apart, whether is was a lone pair or bonding electrons, 5° the angles would be 109 . 5 degrees.

    如果不管它是孤对,还是成,它们等距分开的话,键角是109。

    麻省理工公开课 - 化学原理课程节选

  • But because there's this lone pair here, it's pushing down on the other bonds, 5° so we end up with an angle of less than 109 . 5 degrees.

    但因为这里有孤对,它会把其它向下压,所以键角会小于109。

    麻省理工公开课 - 化学原理课程节选

  • They want to get as far away from each other possible, the ideal angle is 120. But what we have here is a four-membered ring, so what angle does 90° that have to be, that bond? 90 degrees.

    它们想要尽量远离彼此,最理想的是形成120°键角,但现在是个四元环,所以这键角应该多大?

    麻省理工公开课 - 化学原理课程节选

  • This is the easiest question all day, what is the bond angle between all of these?

    这个问题很简单,键角是多少?

    麻省理工公开课 - 化学原理课程节选

  • The bond, it turns out, 5° is 104 . 5 degrees, that h o h bond.

    这个即,HOH键角,是104。

    麻省理工公开课 - 化学原理课程节选

  • So again, if we think about that shape of that carbon atom, it's going to be trigonal planar, 120° it's going to have bond angles of 120 degrees, because we have this set up of having three hybrid orbitals.

    如果我们考虑碳原子的形状,它是平面三形,键角是,因为我们有这三个杂化轨道。

    麻省理工公开课 - 化学原理课程节选

  • So, in a settling, what is the bond angle here?

    这里的键角是多少?

    麻省理工公开课 - 化学原理课程节选

  • What do you know the bond angle should be?

    你们觉得键角是多少?

    麻省理工公开课 - 化学原理课程节选

  • Ok So, according to this model, 90° what we're seeing is a bond angle of 90 degrees.

    我听到不同的答案,OK,,I,hear,a,mix。,根据这个模型,我们看到键角是。

    麻省理工公开课 - 化学原理课程节选

  • So if we still have an angle of a 109 . 5 degrees, and again, we still have four unpaired electrons available for bonding, we can make one of those bonds with another s p 3 hybridized carbon, so we're going to make up one pair here.

    如果键角仍然是109。,同样,我们还有4个未配对的电子可以用来成,我们可以用其中的一个,和另外一个sp3杂化碳原子成,这样我们可以组成一对。

    麻省理工公开课 - 化学原理课程节选

  • So if we do this and we form the molecule ammonia, let's switch to a clicker question, and have you tell me what the bond angle - is going to be in ammonia -- HNH Actually, let me draw it on the board as you look -- actually, can you put the class notes on, since you don't actually have your notes to refer to.

    如果这样做的话,我们就可以形成氨分子,让我们来做一个课堂练习,你们告诉我氨分子中的键角是多少-,键角,the,h,n,h,bond,angle。,实际上让我在黑板上画出它来,这样你们可以看到实际上-,你能把课堂讲义放出来吗,因为你们没有讲义可以参考。

    麻省理工公开课 - 化学原理课程节选

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