It deconvolves that reaction of sodium plus chlorine into elementary steps that are related to electron transfer and acquisition.
它将钠和氯的反应,分解成基本的步骤,这些步骤是直接与电子的转移和获得有关的。
This cation is attracting the chloride next to it and it is repelling the sodium as the next nearest neighbor.
这一阳离子被邻近的氯离子所吸引,并排斥钠离子,因为这是其最邻近的离子。
if we're actually thinking about electron configuration and we look at lithium, sodium and potassium, these all have one valence electron.
让我们来想一想,锂,钠,钾的电子排布,它们都只有一个价电子。
The ones that are most important in physiology are ones that only allow ions to go through: sodium, potassium, chloride, calcium, bicarbonate.
在生理学上这种,只能允许某种离子通过的通道十分重要,这些离子包括钠离子,钾离子,氯离子,钙离子和碳酸氢根离子
We talked about this reaction here where we had chloride ion in the gas phase plus sodium ion in the gas phase.
我们在讨论这一个反应,我们有气相的氯原子,与气相的钠原子接触。
We started with gaseous sodium to make gaseous sodium ion and gaseous atomic chlorine to make gaseous chloride ion through electron transfer.
我们从气态的钠开始,得到气态的钠离子,从气态的氯原子,通过电子转移得到氯离子。
And then I am going to take sodium gas and I am going to make this into sodium gas plus electron.
接下来,将气态的钠,转化为,带正电的气态钠。
For example, sodium in our blood plasma is almost to the point sometimes of 100 millimol or that's very, very concentrated.
比如,钠在我们的血浆中的浓度,有时几乎达到了一百毫克分子,或者说非常非常浓。
We've seen so far that we can have a neutral plus neutral sodium plus chlorine goes to cation plus anion.
到目前为止,我们得到了一个不带电的加一个不带电的,即钠加上氯,得到阳离子加阴离子。
That potential difference is generated by the movement of ions, principally sodium and potassium across the membrane.
电势差是由离子运动造成的,特别是钠和钾的跨膜运动
And they wanted to use a soluble salt of citric acid, so they could have used sodium, they could have used potassium.
而且他们想用一种柠檬酸的可溶性盐,他们本可以用钠,也可以用钾。
I could take an unknown gas and put it in and measure it and then say, wow, those are the lines that are characteristic of sodium.
我取一种未知气体,把它放到管里,然后检测它,哇,这些线是钠的特征。
The first thing I am going to do is I am going to convert the sodium into vapor.
第一步,我将要将固态的钠气化。
So, what happens, this is another view of a sodium channel, so this is actually looking a little bit more at the protein structure.
那么,这里发生了什么,这是钠离子通道的另一张图片,在这种蛋白质结构中,它看起来更复杂一点。
And I say, no, I think any of you should know that potassium lies under sodium.
我要说的是,你们应该知道,钾是在钠的下面的。
So, for example, for sodium, we can instead write neon and then 3 s 1.
所以举例来说对于钠其他的外层电子,的结合的电子。
So now, let's get a sodium here, and the chloride ion next to it to the point where they are touching.
所以,我们要有一个钠离子,和氯离子放在,相互接触的一个点上。
That is to say I can now reroute that sodium plus chlorine reaction and go a different way, but I still end up with the same change in energy.
也就是说,我可以重新定义一种,钠与氯的反应途径,从另一种途径来实现反应,但是能量的变化过程相同。
If you flip the Periodic Table over you will have the ionization energy of sodium, first ionization energy, 5eV and it is about 5 eV which, when you convert, 496kJ/mol is a whopping 496 kilojoules per mole.
如果浏览周期表,你可以得到钠的离子化能,第一电离能,大约,当你转换的时候,是巨大的。
So, I've got something that's one electron away from the electronic structure of neon.
所以,我知道了钠的电子结构和氖,只差一个电子。
Its ionization would be I take one of the electrons on chlorine and throw it away.
这个离子化的过程就是,从钠原子中取出一个电子,并扔掉。
There is nothing saying that that sodium, its positive charge has not been neutralized.
什么也没有,钠的正电荷没有被中和是。
That change happens because something gets triggered in the membrane, and what gets triggered is a voltage gated sodium channel, which is shown here.
变化的原因是膜上某些东西被触发了,被触发的是钠离子电压门控通道,展示在这儿了
For these purposes think about a channel, it only allows sodium to go through for example.
基于此目的,我们来讲离子通道,拿仅允许钠离子通过的通道作为例子
I want to get to there starting from real sodium and real chlorine.
我们要实现这一步,从实际的钠和实际的氯开始。
And, I also know something else about sodium.
另外,我还知道钠的别的性质。
This is denuded of an electron, it is Na plus.
这边是裸电子的,是钠正离子。
The sodium is net positive.
钠离子是带正电的。
So I am already there with sodium.
所以得到了钠的这种形式。
So, for example, if I have a sodium ion over here, and I have a chloride ion over here, where the distance from center to center r I'm denoting as r, this is nucleus to nucleus separation.
所以,比如这有一个钠离子,和一个氯离子,它们中心与中心间的距离,我把它设为,这是原子核和原子和的间距。
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