• So we can actually constructively and destructively combine these waves, these atomic orbitals to make a hybrid.

    我们可以相长,和相叠加这些,这些原子轨道可以杂化。

    麻省理工公开课 - 化学原理课程节选

  • But first, I just want to remind you when we're talking about molecular orbital theory, this is treating electrons as waves, so what we're actually able to do is either constructively or destructively combine atomic orbitals to form molecular orbitals.

    但首先,我要提醒你们,当我们讨论,分子轨道理论的时候,我们把电子看作是一种,所以我们可以相长叠加,或者相叠加这些原子轨道来组成分子轨道。

    麻省理工公开课 - 化学原理课程节选

  • sb So in this case we would have 1 s a and 1 s b, and instead we would subtract one from the other, and what we would see is that instead of having additional, more wave function in the middle here, we've actually cancelled out the wave function and we end up with a node.

    在这种情况下我们有1sa和,两者相减,我们可以看到不是在,中间有了额外更多的函数,而是我们掉了,函数得到一个节点。

    麻省理工公开课 - 化学原理课程节选

  • pxa So what happens when we add a 2 p a and we subtract from it a 2 p x b, or the same with a 2 p y a subtracting a 2 p y b, is that we're actually going to cancel out the wave function in the center, so we now have 2 nodal planes.

    当我们用,减去2pxb时,或者是2pya减去2pyb时,我们会去,中间的函数,所以现在我们有两个节面。

    麻省理工公开课 - 化学原理课程节选

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