• This indicates that by combining two lithiums, the energy of the combined system is lower than the energies of the atomic systems.

    结果显示,两个锂结合后,其结合后的能量,比原子体系的能量

    麻省理工公开课 - 固态化学导论课程节选

  • So when we talk about orbitals in multi-electron atoms, they're actually lower in energy than the corresponding h atom orbitals.

    它们的能量实际上,比对应的氢,原子轨道要

    麻省理工公开课 - 化学原理课程节选

  • Energy may be favoring reaction in one direction, toward let's say products that have lower energy.

    能量上的变化可能支持反应,向着产物具有更低能量的方向进行。

    麻省理工公开课 - 热力学与动力学课程节选

  • You can see low voltage, low energy, high voltage, high energy. It is a linear function.

    你会看到,电压,低能量,高电压,高能量,这是种线性关系。

    麻省理工公开课 - 固态化学导论课程节选

  • So, similarly in a case where instead we have a small energy difference, we're going to have a low frequency, which means that we're going to have a long wavelength here.

    在这个例子里,能量差较小,我们得到的频率,这意味这它的波长更长。

    麻省理工公开课 - 化学原理课程节选

  • They're not interacting at all so that's why the energy is the same as that for two individual atoms, that's what we're dealing with. As we get closer together, we start get lower and lower in energy.

    它们之间没有任何相互作用,因此,体系的能量就等于两个分开的原子的能量,这就是我们要处理的,而随着我们的距离越来越近,我们的能量开始变得越来越

    麻省理工公开课 - 化学原理课程节选

  • The z effective is lower, so we have to put less energy in to get an ion out.

    它的有效核电量更,所以我们只需要更少的能量就能打出一个离子。

    麻省理工公开课 - 化学原理课程节选

  • So we know we always want to have our systems in as low an energy as possible, so it makes sense that a bond would happen any time we got a lower energy when we combine two atoms, versus when we keep them separate.

    我们知道我们总是希望使我们的系统,处于能量尽可能的状态,因此就应该有化学键产生,一旦我们合并两个原子之后体系的能量变得更,相较于分开时。

    麻省理工公开课 - 化学原理课程节选

  • So what I want to point out is 3d2 what we said now is that the 3 d 2 is actually lower in energy, so if we were to rewrite this in terms of what the actual energy order is, 3d2 4s2 we should instead write it 3 d 2, 4 s 2.

    所以我们想指出的是,我们现在所说的是,实际上能量比较,所以如果我们重新的,写出实际的能量顺序,我们应该写出。

    麻省理工公开课 - 化学原理课程节选

  • So, in other words, this c l minus is actually lower in energy than the reactants were.

    也就是说,负一价氯离子,比原来的反应物的能量

    麻省理工公开课 - 化学原理课程节选

  • And when we say lower in energy, of course, what we mean is more negative.

    当然当我们说能量时,我们的意思是更为不活跃。

    麻省理工公开课 - 化学原理课程节选

  • That makes sense because we're losing energy, we're going to a level lower level, so we can give off that extra in the form of light. And we can actually write the equation for what we would expect the energy for the light to be.

    这很合理,因为我们在损失能量,我们要到一个更的能级去,我们要以光的形式给出额外的能量,我们可以写下光能量的方程。

    麻省理工公开课 - 化学原理课程节选

  • And that's going to be lower in energy than the two individual atomic orbitals.

    它的能量要比,两个独立的原子轨道能量

    麻省理工公开课 - 化学原理课程节选

  • Those are going to be the more stable or the lower energy structures.

    这种结构应该是更稳定的,或者能量的结构。

    麻省理工公开课 - 化学原理课程节选

  • Why don't you use something that has much lower energy?

    为什么你不用一些,能量的东西呢?

    麻省理工公开课 - 固态化学导论课程节选

  • All right. So formal charge can actually help us out when we're trying to decide between several Lewis structures that look like they might be comparable in terms of which might be the lower energy or the more stable structure.

    好的,形式电荷真的可以,帮助我们决定,在几种路易斯结构中,哪个更可能符合能量,或者结构更稳定的要求。

    麻省理工公开课 - 化学原理课程节选

  • So it's going to be favorable for the electrons instead to go to that lower energy state and be within the molecular orbital.

    所以对于电子来说,更倾向于能量的轨道,呆在分子轨道里。

    麻省理工公开课 - 化学原理课程节选

  • So, we see that the two h atoms separate have a certain energy that's lower than when the electron's not with the atom.

    那么,我们看到两个分开的氢原子所具有的能量,比原子中没有电子时更

    麻省理工公开课 - 化学原理课程节选

  • And what you can see directly from looking at this energy level diagram, is that the molecule that we have is now more stable in the individual atoms.

    你从直接看,能级图中会发现,分子比单个的,原子能量

    麻省理工公开课 - 化学原理课程节选

  • So, in fact, yes, we did confirm that these covalent bond, at least in the case of hydrogen, we have confirmed by the numbers that we are at a lower energy state when we talk about the bonded atom versus the individual atom.

    因此,事实上,是的,我们证实了共价键,至少在氢这种情况下,我们通过数据证实了,成键的原子处于能量的状态,当其与单个的原子相对比时。

    麻省理工公开课 - 化学原理课程节选

  • That makes sense because we're lower in energy, the electrons are now lower in energy.

    这很好理解,因为我们降能量,电子能量

    麻省理工公开课 - 化学原理课程节选

  • So, in talking about covalent bonds, we should be able to still apply a more general definition of a chemical bond, which should tell us that the h 2 molecule is going to be lower in energy than if we looked at 2 separate hydrogen atom molecules.

    那么,既然提到了共价键,我们应该还可以,给化学键下一个更普遍的定义,那就是告诉我们氢分子能量应该更,与两个分开的氢的单原子分子相比。

    麻省理工公开课 - 化学原理课程节选

  • It's a more negative energy, it's a lower energy state.

    负号表示能量

    麻省理工公开课 - 化学原理课程节选

  • Absorption is just the opposite of emission, so instead of starting at a high energy level and dropping down, when we absorb light we start low and we absorb energy to bring ourselves up to an n final that's higher.

    吸收就是发射的逆过程,与从一个高能量低能量不同,当吸收光时,我们从低能量开始,吸收能量到一个更高的能量

    麻省理工公开课 - 化学原理课程节选

  • So this is our lower energy structure.

    因此这是能量的结构。

    麻省理工公开课 - 化学原理课程节选

  • So, we're going to start with talking about bonding, and any time we have a chemical bond, basically what we're talking about is having two atoms where the arrangement of their nuclei and their electrons are such that the bonded atoms results in a lower energythan for the separate atoms.

    那么,下面我们将从成键开始讲起,无论什么时候我们有一个化学键,基本上我们所讨论的,都是如何安排两个原子的原子核的位置,与电子的位置使得成键的两个原子,最终比分开时的能量

    麻省理工公开课 - 化学原理课程节选

  • So whenever we're thinking about energy states, it's lways more stable to be more low in an energy well, so that's why it makes sense that it's favorable, in fact, to have an electron interacting with the nucleus that stabilizes and lowers the energy of that electron by doing so.

    负的能量越多,能级越,无论何时,能级总是越越稳定,所以这就是为什么电子更,倾向于通过和原子核相互作用,来稳定并降电子的能级。

    麻省理工公开课 - 化学原理课程节选

  • The reason it's aluminum is because aluminum has a lower z effective, so it's not being pulled in as tightly by the nucleus, and if it's not being pulled in as tightly, you're going to have to put in less energy in order to ionize it, so that's why it's actually going to have the smaller ionization energy.

    原因是,铝的有效核电量更少,所以没有被原子核束缚得更紧,而如果没有被束缚得更紧,你为了电离它所需要注入的能量也就更少,这就是,它的电离能会更的原因。

    麻省理工公开课 - 化学原理课程节选

  • But we could, for example, look at a case where we have several different structures that look pretty good, and the one we want to determine as being the lowest energy structure is the one in which the absolute values of the formal charges are going to be lower, so essentially that they have less charge separation.

    但是我们可能,比如,遇到一种情况,有好几个候选的路易斯结构看起来都挺好的,这时候我们就需要,通过比较哪个形式电荷的绝对值更,来决定哪个结构的能量,本质上这个结构中分开的电荷更少。

    麻省理工公开课 - 化学原理课程节选

  • we start high and go low, we're dealing with emission where we have excess energy that the electron's giving off, and that energy is going to be equal the energy of the photon that is released and, of course, through our equations we know how to get from energy to frequency or to wavelength of the photon.

    当我们从高到时,我们说的,是发射,电子有多余的能量给出,这个能量等于,发出,光子的能量,当然我们可以通过方程,从能量知道,光子的频率,和波长。

    麻省理工公开课 - 化学原理课程节选

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