• But now it's going to make more sense because in that case we were just talking about single electron atoms, and now we're talking about a case where we actually can see shielding.

    但是现在能讲得通了,因为在那个情况中我们仅仅是现在我们讨论的是,讨论单电子原子,看到屏蔽的案例,我们能看到屏蔽。

    麻省理工公开课 - 化学原理课程节选

  • So what we'll have here is a trigonal planar case, and you can see that we only have three electrons that are set for bonding, so we'll add three hydrogens, and for b h 3, we'll get a stable structure here.

    让电子劲量远离的时候,不用考虑它,这个例子是平面三角形,你可以看到,只有3个电子可以成键。

    麻省理工公开课 - 化学原理课程节选

  • We're going to see an example of that in a second. What we really want to worry about, what's the worst case that happens.

    我们接下来就来看一个这样的例子,我们要关注的是,发生的最坏情况是什么呢?

    麻省理工公开课 - 计算机科学及编程导论课程节选

  • Now at the very bottom, should we see a default case.

    现在在最下面,我们会看到一个default,分支。

    哈佛公开课 - 计算机科学课程节选

  • So what we see is that structure a is the most stable because we have the least separation of charge in the case of structure a.

    因此我们看到结构,A,应该是最稳定的,因为这种情况下,分开的电荷最少。

    麻省理工公开课 - 化学原理课程节选

  • So, it turns out that in this case, 2 p and any time that we see we're going from a 2 s to 2 p, filling in of electrons, we actually see that little bit of glitch in ionization energy.

    在这种情形下的结果就是,任何时候我们从,2,s,到,填充进电子,我们都会看到电离能会稍稍偏离我们的规律。

    麻省理工公开课 - 化学原理课程节选

  • So we can think of a third case where we have the 3 s orbital, and in the 3 s orbital 0 we see something similar, we start high, we go through zero, where there will now be zero probability density, as we can see in the density plot graph.

    第三个例子那就是,3s轨道,在3s轨道里,我们看到类似的现象,开始非常高,然后穿过,这里,概率密度是0,就像你们在概率密度图里看到一样,然后我们到负的。

    麻省理工公开课 - 化学原理课程节选

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