• And the significant difference between s orbitals and p orbitals that comes from the fact that we do have angular momentum here in these p orbitals, is that p orbital wave functions do, in fact, have theta and phi dependence.

    轨道和p轨道的,不同之处在于,在p轨道,波函数,随theta和phi变化。

    麻省理工公开课 - 化学原理课程节选

  • So they're the same shape, this is the shape of the orbital or the shape of the wave function, and we can call this either 2 p x a being combined with 2 p x b, or we could say since it's the same shape, it's 2 p y a being combined with 2 p y b.

    它们形状是一样的,这是轨道的形状或者波函数的形状,我们叫它2pxa和2pxb结合,或者我们说因为它们的形状是一样的,它是2pya和2pyb结合。

    麻省理工公开课 - 化学原理课程节选

  • pxa So what happens when we add a 2 p a and we subtract from it a 2 p x b, or the same with a 2 p y a subtracting a 2 p y b, is that we're actually going to cancel out the wave function in the center, so we now have 2 nodal planes.

    当我们用,减去2pxb时,或者是2pya减去2pyb时,我们会消去,中间的波函数,所以现在我们有两个节面。

    麻省理工公开课 - 化学原理课程节选

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