So this one is spin-up plus a half, this is spin-down minus a half.
所以自旋向上是正二分之一,而自旋向下是负二分之一。
Negative 1 plus 0 should add up to negative 1, if in fact, we're correct for the c n anion.
负一加上零应该等于负一,如果是这样,我们对于氰离子的结果就是正确的。
00 Suppose that being alive per se is worth plus a hundred points, just to make up some number.
假设活着本身价值超过,这只是例举数字说明。
Cv+R=Cp Cv is equal, oh Cv plus R is equal to Cp it's a relationship that we had up here that we wanted to prove.
我们就得到了,我们一开始,想要证明的。
That is to say I can now reroute that sodium plus chlorine reaction and go a different way, but I still end up with the same change in energy.
也就是说,我可以重新定义一种,钠与氯的反应途径,从另一种途径来实现反应,但是能量的变化过程相同。
Whatever happens to me, when it's spread out over six billion plus people, it ends up divided by six billion and it becomes unobservable.
发生在我身上的事,分散到六十多亿人口上,被六十亿除,就变得难以察觉。
And if I pull it out one more level, 12k it's 12 plus 12 plus t of b over 8, 12 k because I'll have 12 of those to add up, plus t of b over 2 to the k.
总结一下也就是说,在k步以后,总步数应该是,那这种情况什么时候才能停止呢?,才能到达最基本的情况呢?
Remember, you've got to keep track of the sign of acceleration, so if you're picking up speed towards the ground, a is negative, so it will be g plus a, but a is a negative number.
记住,一定要注意加速度的符号,所以当你加速下降的时候,a 是负的,还是 g 加上 a,但是 a 是负数
/2 You can have it equal to plus 1/2, and that's what we call spin up, 1/2 or you can have it equal to minus 1/2, which is what we call spin down.
它可能会等于,我们叫它自选朝上,或者它等于负,我们叫它自旋朝下。
So we can do this for any final charge we have, if we have a molecule that has a charge of plus 2, then all of the formal charges should add up to plus 2 and so on.
对于任意净电荷的情况,我们都可以这样做,比如假设我们有一个带两个正电荷的分子,那么所有的形式电荷加起来应该等于正二,等等。
w And that has to equal q plus w, summed up for all the steps.
等于q加,对所有过程相加。
If we look at our last structure here where we have nitrogen the middle, we can also figure out all those formal charges, and in this case we have plus 1 on the nitrogen, we have minus 2 on the carbon, and then we end up with a 0 on the sulfur there.
如果我们来看看最后一个结构,在中间的原子是氮,我们同样可以计算出所有的形式电荷,而在这种情况下,氮为正一,碳为负二,而最后硫为零。
OK, delta H is delta of u plus pV. By definition that's how we define enthalpy up here.
好,ΔH=Δ,根据定义,这就是我们。
2 So what we end up saying is that the z effective or the effective charge that that first electron feels is now going to be plus 2.
第一个电子感觉到的有效的z或者有效电荷现在是,我们再一次将它带入我们的方程。
And then we end up having 6 shared electrons, 2 from each of the bonds, so we end up with a formal charge on sulfur of plus 1.
然后我们有六个共用电子,每个键两个,因此最终硫的形式电荷量为正一。
The highest occupied orbital is now the 2 s orbital, 1 s 2 2 s 1 so we're going to end up with boron 2 plus 1 s 2, 2 s 1, plus the electron coming out of there.
现在最高的被占据轨道是,2,s,轨道,因此结果应该是正二价的硼,再加上一个出射的电子。
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