• So that means that the more stable molecule is going to be this molecule here, which actually puts the negative charge on be more electronegative atom.

    因此这意味着更稳定的分子,应该是这一个,它真正把负的电荷放到了,电负性更高的原子上。

    麻省理工公开课 - 化学原理课程节选

  • And we haven't talked about reactions at all yet, so you don't need to worry about the specifics of that exactly, but just that if you have this negative change in energy, you have a more stable product than you do reactant.

    当然我们还没有开始讨论反应,所以你不用担心它的细节是怎么样的,你只需要知道,如果能量的变化是负值,那么你将得到一个比反应物更稳定的生成物。

    麻省理工公开课 - 化学原理课程节选

  • And what you can see directly from looking at this energy level diagram, is that the molecule that we have is now more stable in the individual atoms.

    你从直接看,能级图中会发现,分子比单个的,原子能量更低。

    麻省理工公开课 - 化学原理课程节选

  • The reason this an exception is because it turns out that half filled d orbitals are more stable than we could even predict.

    这个例外的原因是因为,半填充d轨道比,我们预期的填充方式更加稳定。

    麻省理工公开课 - 化学原理课程节选

  • You wouldn't be expected to be able to guess that this would happen, because using any kind of simple theory, we would, in fact, predict that this would not be the case, but what we find experimentally is that it's more stable to have half filled d orbital than to have a 4 s 2, and a 3 d 4.

    你们不用预期有能力,猜出这个会发生,因为使用任一种简单的理论,我们事实上可以预测不会是那种情况,但是我们在实验中发现的,是半填充d轨道比,4s23d4更加稳定。

    麻省理工公开课 - 化学原理课程节选

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