All right. So let's look at some of these wave functions and make sure that we know how to name all of them in terms of orbitals and not just in terms of their numbers.

好，让我们来看一下,这些波函数,并确定我们都知道,怎么用轨道,而不仅是量子数来命名它们,一旦我们可以命名它们。

麻省理工公开课 - 化学原理课程节选

We started talking about these on Wednesday, and what we're going to start with is considering specifically the wave functions for multi-electron atoms.

我们从周三开始讨论这些，而且我们将要以特别地考虑,多电子原子的波函数,为开始。

麻省理工公开课 - 化学原理课程节选

And we can also write this in an even simpler form, which is what's called electron configuration, and this is just a shorthand notation for these electron wave functions.

而且我们也可以将它，写为一个更简单的形式，它叫做电子构型,这个仅仅是这些电子波函数的。

麻省理工公开课 - 化学原理课程节选

So instead, these would be canceling out wave functions between the two, so we would end up with a nodal plane down the center.

相反，两者之间的,波函数会相互抵消，所以我们在中间会得到一个节面。

麻省理工公开课 - 化学原理课程节选

And the significant difference between s orbitals and p orbitals that comes from the fact that we do have angular momentum here in these p orbitals, is that p orbital wave functions do, in fact, have theta and phi dependence.

轨道和ｐ轨道的,不同之处在于,在ｐ轨道，波函数，随theta和phi变化。

麻省理工公开课 - 化学原理课程节选

So we can draw that for 1 s a, we can also draw it for 1 s b, and what I'm saying for the molecular wave function is that we have the interference between the two, and we have a constructive interference, so we end up adding these two wave functions together.

所以我们可以对1sa画出它来，我们也可以对1sb画出它来，对于分子波函数我要说的是,它们两者之间会干涉，这里我们有相长干涉，所以我们得到的是波两个波函数加起来。

麻省理工公开课 - 化学原理课程节选