And we find the same thing for these two atoms here, it's not actually a double bond, it's somewhere between a single bond and a double bond.
而且我们发现这两个原子的情况是一样的,它其实不是一个双键,而是介于单键与双键之间的。
This is very easy molecule because we know exactly where to put them without even having to think, we only have one option, and we'll make a triple bond between the carbon and the nitrogen.
这个分子非常简单,因为我们知道应该把它们放在哪里,甚至不用去想,我们只有一个选择,我们将在碳与氮之间形成一个三键。
This energy level diagram helps us understand the relationship between electron filling and bond strength.
能级图能帮助我们,理解电子填充,和键强的关系。
So the point is, this balance between energy thatyou could think of as say bond energies in chemical reactions, and entropy that you can think of in terms of disorder, how many different possible combinations or configurations of something wrong, will dictate where the equilibrium lies.
关键在于,这种能量与熵之间的平衡,确定了平衡的条件,在化学中能量涉及键能,而熵和无序有关,即有多少可能的不同组合或者形位,二者的平衡会告诉我们平衡态是什么样子。
Just as I foreshadowed, if you look at the difference between the first and third quartile in the bond market -these are active returns over a ten-year period again ending June 30,2005 -and the fixed income market, the difference between first and third quartile is a half a percent per annum.
如我之前所示,如果观察,债券市场中的第一和第三个四分位数,四分位数即统计学中,把所有数值由小到大排列并分成四等份三个分割点位置分别就是三个四分位数 考虑十年期的主动型的收益,截止于2005年6月30日,在债券这个固定收益市场,第一和第三个四分位数,每年只差0.5%
And we know that it's electron density between the nuclei that holds two atoms together in a bond.
我们知道是两个原子核之间的,电子密度保持两个原子在一起成键的。
And we can also talk about the bond length, so we might be interested in what the bond length is, what the distance between these two nuclei are.
另外一点就是键长,我们对键的长度也感兴趣,也就是两个原子核之间的距离。
This is the easiest question all day, what is the bond angle between all of these?
这个问题很简单,键角是多少?
So that is the bond axis it's just the axis between the two nuclei.
这就是键轴,它就是两个原子核之间的轴。
If we have the molecule ethane, then what we're going to have first is our sigma bond that we described between the two carbons.
如果我们有乙烷分子,那我们首先有,碳碳之间的sigma键。
Our second bond is going to be between the carbon and the hydrogen atoms.
第二种键是,碳氢之间的键。
So it's along the bond axis and it's between a carbon s p 2 hybrid, and then the hydrogen is just a 1 s orbital that we're combining here.
所以它是沿着键轴方向的,而且这里是一个碳sp2杂化轨道,和一个氢的1s轨道的结合,在这里我们可以合并他们。
If we have, coming along this z axis, another carbon atom, we can actually form one bond between the two carbon atoms there.
如果我们在z方向,有另外一个碳原子,我们可以在,两个碳原子之间形成一个键。
When we're talking about r for internuclear distance, we're talking about the distance between two different nuclei in a bond, in a covalent bond.
当我们说,r,代表的是核间距的时候,我们讨论的是一个距离,在一个键--一个共价键的两端的原子核之间的距离。
And again, this is between the p orbitals, these are not hybrid orbitals, so when we name this bond we're going to name it as a pi bond here, because it's between two p orbitals, and it's going to be between the carbon 2 p y orbital, and the other carbon 2 p y orbital.
同样,这是在p轨道之间的,它们不是杂化轨道,所以当我们命名这个键时,我们要命名它为π键,因为它在两个p轨道之间,而且是在碳2py轨道,和另一个碳2py轨道之间。
So that's two of our types of bonds in benzene, and we have one type left, that's going to actually be the double bond or the pi bond that So we can have one bond here between this carbon's p orbital and this carbon's p orbital.
这就是苯环里的两种键,我们还剩一种,那就是这些p轨道之间,形成的双键或者π键,我们可以在这个碳的p轨道,和这个碳的p轨道之间有个键。
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