• So you might ask well, why are we using this model if it clearly doesn't take into account quantum mechanics?

    那么大家可能会问为什么我们要用这个,显然没有考虑量子力学的模型呢?

    麻省理工公开课 - 化学原理课程节选

  • But at the time, they didn't have a well-formed name for it, they were just saying OK, there's this fourth quantum number, there's this intrinsic property in the electron.

    但在那时,人们没有给它取名,他们只是说ok,这是第四个量子数,这是电子的本征性质, 

    麻省理工公开课 - 化学原理课程节选

  • We use the adjective "Newtonian" but we don't speak of certain writers who are still interested in quantum mechanics as "Newtonian writers."

    虽然我们用牛顿主义者这个词“,但是我们不会把那些,对量子力学有兴趣的人称作牛顿主义作家“

    耶鲁公开课 - 文学理论导论课程节选

  • Some of you are probably going to be doctors and you don't know why I'm going to do special relativity or quantum mechanics, but you don't know when it will come in handy.

    你们中的有些人可能会成为医生,但你们现在不能理解,我为什么要讲相对论和量子力学,但是说不定什么时候,你就用上了呢

    耶鲁公开课 - 基础物理课程节选

  • But the reality that we know from our quantum mechanical model, is that we can't know exactly what the radius is, all we can say is what the probability is of the radius being at certain different points.

    我们不可能准确的知道,半径是多少,我们只能说,它在不同半径处,的概率是多少,这是,量子力学。

    麻省理工公开课 - 化学原理课程节选

  • We didn't just need that n, not just the principle quantum number that we needed to discuss the energy, but we also need to talk about l and m, as we did in our clicker question up here.

    我们不仅需要n,不仅要这个可以,决定能量的主量子数,还需要m和l,就像我们做这道题这样。

    麻省理工公开课 - 化学原理课程节选

  • So, let's see how some of this works, and hopefully your counterparts from 100 years ago would also be able to think about how this works, even if they don't have the quantum mechanics behind the individual electron configurations for atoms.

    那么,下面让我们来看一下它是怎么用的,希望一百年前想你们一样的同学,也能够弄懂它为什么能用,尽管他们没有量子力学,不知道原子的电子排布。

    麻省理工公开课 - 化学原理课程节选

  • Or, if you're a pediatrician with a really small patient who will not sit still, it's because the laws of quantum mechanics don't allow an object to have a definite position and momentum.

    或者你是个儿科医生,而你的小病人却总也坐不住,这是因为量子力学,不允许物体同时具有确定的位置和动量

    耶鲁公开课 - 基础物理课程节选

  • So let's go to a second clicker question here and try one more. So why don't you tell me how many possible orbitals you can have in a single atom that have the following two quantum numbers?

    让我们来看下一道题目,你们来告诉我,有多少个可能的轨道,含有这些量子数呢?

    麻省理工公开课 - 化学原理课程节选

  • All right, so hopefully if you see any other combination of quantum numbers, for example, if it doesn't quickly come to you how many orbitals you have, you can actually try to write out all the possible orbitals and that should get you started.

    所以希望你们如果遇到,任何其它的量子数组合的问题,如果你们不能马上想到有多少个轨道,可以试着先写出所有的轨道,这是个不错的切入点。

    麻省理工公开课 - 化学原理课程节选

  • And when we talk about l it is a quantum number, so because it's a quantum number, we know that it can only have discreet values, it can't just be any value we want, it's very specific values.

    当我们讲,l是一个量子数时,因为它是量子数,我们知道,它只能去分立的值,它不能取到所有的数,它取一些确定的数。

    麻省理工公开课 - 化学原理课程节选

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