In that case point p 1 doesn't correspond to this point, it actually corresponds to the point of radius 2 and angle 1, which is about here.
基本上也就是说这是第一个点1,这是第二个点,把它们的值加到一起,然后我就得到了目标点,好,这听起来挺不错的。
p Well, it's not just p dS/dV because there's some dS/dV at constant T.
它不是简单的,因为式子中还包含,恒定温度下的。
It can't just be a matter of not P-functioning.
肯定不止和人格功能性有关。
So it might look like here, if you don't understand about p orbitals, which I know all you do, but if someone else was just looking and seeing, it kind of looks like there's two bonds here.
这里看起来有点像,如果你们不知道p轨道的话,我知道你们都知道,但如果另外有个人看到这个,这看起来有点像两个键。
That's different when you have continuous values-- you don't have P because it's always zero.
和离散型随机变量的分布不同的是,连续型随机变量的分布中,某一点的概率值始终是零
So when I type, I'm sorry, I shouldn't say type, c point although I would have typed it, p dot x, here's what basically happens.
处于特定点的实例的这个概念,我知道它来自于这个类,这个类,when,I,write,因此当我输入,抱歉,我不该说输入的,当我写,虽然我需要输入它,p,x的时候。
Texts that insist on a central sanctuary are probably Josiah's time or later. And there are many sections of P that don't seem to assume a central sanctuary.
一些章节坚持中心圣所,则可能在约西亚或之后时期,P资源中有很多部分,并没有呈现出一个中心圣所。
Again, so as we don't get confused, normally we use S for strategy, but let's use P since they're prices.
为了避免混淆,通常我们用S表示策略,但是这次我们使用P,因为它代表价格
pV=RT p plus a over v bar squared times v bar minus b equals r t. All right if you take a equal to zero, these are the two parameters, a and b. If you take those two equal to zero you have p v is equal to r t.
我们就回到,也就是理想气体,状态方程,下面我们来看看,这个方程。
V So it's minus T dV/dT at constant p, plus V.
负的T乘以恒定压强下dV/dT,再加上。
That's why we said on the personality theory,as we went ahead in time, once the P-functioning stops,I don't exist anymore.
这就是为什么根据人格理论的说法,随着时间流逝,人格功能停止,我也不再存在。
Well, the initially tempting thing to say is not only aren't you broken, but you're actually engaged in P-functioning.
首先要说的会是,不仅你没有被破坏,还有确实,拥有人格功能性。
But if death means permanent cessation of P-functioning, then it turns out the dead weren't really dead after all.
但如果死亡指的是人格功能性的永久停止,那就说明死者并非死去。
It's somewhat different when we're talking about the p or the d orbitals, and we won't go into the equation there, but this will give you an idea of what we're really talking about with this radial probability distribution.
当我们讨论p轨道或者,d轨道的时候会有些不同,我们那时不会给出方程,但它会给你们一个,关于径向概率,分布的概念。
So the most basic answer that doesn't explain why is just to say well, the s orbital is lower in energy than the p orbital, but we now have a more complete answer, so we can actually describe why that is.
所以最基本的答案是那没有解释,所以我们事实上可以描述,为什么是那样,但是我们现在有一个更复杂的答案,又是有效电荷量。
TdS It comes from the fact that dq reversible is T dS, pdV and dw reversible is minus p dV.
这个结论来自于:可逆过程下dq等于,做功dw等负的。
Well,you can't tell by thinking about the normal case, because the B-functioning and the P-functioning stop at the same time.
这从通常的例子中是研究不出来的,因为生理功能和人格功能同时结束。
Remember, we didn't hybridize the 2 p y orbital, so that's what we have left over to form these pi bonds.
记住,我们并没有杂化2py轨道,这是我们剩下的那个行成了π键。
But we don't have a P-functioning body.
但这不是具有人类能力的肉体
du external dV minus T surroundings dS is less than zero.
加上压强p,du,plus,p,乘以dV减去环境温度T乘以dS小于零。
And the useful outcome of all that is that p we get to see how entropy changes with one of those variables in terms of only V, T, and p, which come out of some equation of state.
这样做的重要结果是,我们得到了熵随着V,T或者,其中一个变量变化的情况,这些可以从状态方程得到。
du/dV So now our du/dV, dp/dT at constant T is just T times dp/dT which is just p over T minus p, it's zero.
现在我们的恒定温度下的,等于T乘以dp/dT,在这里,等于p除以T,最后再减去p,结果是0。
T Remember, we're trying to get delta H, p we're trying to get dH/dT constant pressure and dH/dp constant temperature. OK, these are the two things were trying to get here.
想要得到在恒压状态下的偏H偏,和在恒温状态下的偏H偏,好的,这是两个我们,在这里想要得到的东西。
du/dT constant pressure is the direct derivative with respect to temperature here, which is sitting by itself under constant volume keeping this constant but there is temperature sitting right here too.
偏U偏T,p恒定是对,温度的直接微分,而它本身对体积不变,保持它不变,但是这里也有一个温度,这就是偏U偏V,T恒定。
Remember, we don't do a one-to-one correlation, because p x and p y are some linear combination of the m plus 1 and m minus 1 orbital.
记住,我们不需要把它们一一对应,因为px和py轨道是,m等于正负1轨道的线性组合。
G P Thompson And it turns out that G.P. Thompson, and I'm sure this wasn't the case, but I like to think of it as a little bit of child rebelling against the father.
结果是他的儿子,我确定不是那种情况,但是我们认为他在小时候,对他的父亲可能有一点叛逆。
If T is less than T inversion, you have the opposite case, and dT/dp is greater than zero.
如果T比转变温度低,情况就相反,偏T偏p大于零。
应用推荐