So, in order to fill our octet, what we do is put two on the nitrogen and two on the carbon.
因此,为了填满我们的“八隅体“,我们需要将两个放到氮上,将另外两个放到碳上。
So, electron promotion does not happen in terms of nitrogen, because it would not increased our number of unpaired electrons.
这里对于氮原子不会有电子激发,因为这不会增加,未配对电子的数目。
We know nitrogen bonds multiple bonds, so let's look at nitrogen.
我们了解氮气中有多重键,我们看看氮气。
So what we can actually directly compare is the dissociation energy or the bond strength of nitrogen versus hydrogen.
因此实际上我们可以直接进行比较,对氮分子与氢分子的离解能,或键的强度。
So in terms of nitrogen that starts off with a valence number of 5, again we have 2 lone pair electrons in the nitrogen, and again, we have 6 electrons that are shared.
对于氮来说,我们应该从五个价电子开始,同样,氮也有两个孤对电子,共用电子的个数也一样,是六个。
We know that ionization energy is going to increase as we go across the periodic table, so that means carbon has a lower ionization energy than nitrogen which is right next to us.
我们知道电离能会随着周期表,向右而逐渐变大,因此碳的电离能比旁边的氮要低一些,那么就像我说的。
So if we take a look at nitrogen here, what you'll notice is we have thre available for bonding, - and we already have our lone pair -- one of our orbitals is already filled up.
如果我们看一下氮原子,我们注意到我们可以成3个键,我们已经有一个孤对-,其中的一个轨道已经被填满了。
So, in this case, we see that our formal charge is negative on the nitrogen, in this case it's negative on oxygen.
那么,在这种情况下,我们看到氮的形式电荷是负的,而在这种情况下,氧的是负的。
So that explains one of our glitches here, but we have another glitch, and that second glitch comes between nitrogen and oxygen.
那么我们的第一种小偏差已经解释清楚了,但是我们还有另外一种,它在氮和氧之间发生。
So this means nitrogen has low electron affinity, it doesn't actually want to gain an electron.
这意味着氮的电子亲和能很低,它实际上并不愿意得到一个电子。
So, if we took the case of nitrogen, if we add an electron to nitrogen and go to n minus, we find that the change in energy is 7 kilojoules per mole.
如果我们以氮为例,如果我们给氮增加个电子令它变成-1价的氮,我们会发现能量的变化是,7,千焦每摩尔。
So, if we talked about a nitrogen-nitrogen single versus double versus triple bond, the triple bond will be the shortest and it will be the strongest.
因此,如果我们讨论的是氮与氮之间的单键,双键与三键,那么三键应该是其中最短的一个,同时也是最强的一个。
We see that the radius is shorter, so that means that the nitrogen-nitrogen bond is going to be shorter.
我们看到这个距离更短,这就意味着,氮与氮之间的键应该更短。
So, shared electrons are the ones that are shared between the carbon and the nitrogen, so we have 6 shared electrons, and we want to take 1/2 of that.
共用电子是那些在碳和氮之间,被它们共用的电子,那么我们有六个共用电子,然后我们要给它乘上二分之一。
So we can put actually all 4 of our extra electrons in between the carbon and the nitrogen.
因此我们可以把这剩下的,四个电子都放在碳和氮之间。
So in our first structure, we would find for the nitrogen we have a formal charge 5 minus 4 minus 2, because we're starting with 5 valence electrons, so that is a formal charge of minus 1.
那么在我们的第一个结构中,我们发现氮的形式电荷量是五减去四4,再减去二,因为我们开始有五个价电子,因此它的形式电荷量是负一。
So that takes care of the hydrogen, what about between the carbon and the nitrogen?
因此氢就被排除了,那么碳和氮呢?
So, nitrogen is shown here, we know that because it has 7 electrons.
那么这里显示的是氮,我们能看出来是因为它有七个电子。
So what we see is that the formal charge on the nitrogen is 0.
因此我们看到氮的形式电荷是零。
So, let's, for example, look at nitrogen. So n 2, we can do the chart here in green, so it's the green dotted line, and what we see is that we have now defined this energy as where the 2 nitrogen atoms are separated.
那么,让我们举个例子,看一下氮,那么氮分子,我们可以把它用绿色曲线画在这,这是绿色的虚线,可以看到,我们已经定义为零点能,当两个氮原子分离时。
But for anything 7 or less, so what is the atomic number for nitrogen?
但对于7或者更少,对于N原子序数是多少?
So if we're comparing the difference between these 2 now, what you'll notice is that in nitrogen we have all half-filled 2 p orbitals, and now, once we move into oxygen, we actually have to add 1 more electron into 1 of the 2 p orbitals.
那么如果我们来比较下它们两个有什么不同,你会发现氮的,2,p,轨道,都是半满的,现在,我们继续看一下氧,我们不得不在其中一个,2,p,轨道上,再放上一个电子。
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