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But now it's going to make more sense because in that case we were just talking about single electron atoms, and now we're talking about a case where we actually can see shielding.
但是现在能讲得通了,因为在那个情况中我们仅仅是现在我们讨论的是,讨论单电子原子，看到屏蔽的案例,我们能看到屏蔽。
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We also need to follow Hund's rule, this is that a single electron enters each state before it enters a second state.
我们也需要遵从洪德规则，这是一个电子在进入第二个态之前,要进入每一个态。
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And, it involves a single electron orbiting a positively charged nucleus.
包含了一个单独的电子轨道,一个带正电荷的核。
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That makes sense because we know that every single electron has to have its own distinct set of four quantum numbers, the only way that we can do that is to have a maximum of two spins in any single orbital or two electrons per orbital.
那个讲得通,因为我们知道每一个电子,都有它自己独特的量子数,我们能做的唯一方式是,在任一单个轨道中最多有两个自旋电子,或者每个轨道有两个电子。
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Well, we can't guarantee with UV light we'll have enough energy to eject every single electron, so that's why when we use x-rays, they're higher energy, you can pretty much be guaranteed we're going to eject all of those electrons there.
好，我们不能保证紫外光有足够的能量,激发出每一个电子，所以我们要使用，X，射线，它的能量更高，你可以非常确定,我们可以激发出其中所有的电子。
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And by state we just mean orbital, so if we're looking at the p orbitals here, x that means that a single electron goes in x, and then it will go in the z orbital before a second one goes in the x orbital.
我们说的态仅仅意味着轨道，所以如果我们观察这里的p轨道，那意味着单个电子进入，然后它会进入z轨道,在它第二个进入x之前。
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We're going to get to more complicated atoms eventually where we're going to have more than one electron in it, but when we're talking about a single electron atom, we know that the binding energy is equal to the negative of the Rydberg constant over n squared, so it's only depends on n.
我们以后会讲到，更加复杂的情况,那时候,不只有一个原子，但当我们讲，单个原子的时候，我们知道结合能，等于,负的Rydberg常数,除以n平方，所以它仅仅由n决定的。
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So we can actually pop an electron or eject an electron from any single orbital that is occupied within the atom.
任何一个被占据轨道,打出一个电子,或者说发射出一个电子。
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Yes. In fact, there is not enough energy in a single photon to go ahead and eject an electron from this zinc surface.
是的，事实上，这里的光子没有足够的能量,去从锌表面逐出一个电子。
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And what they could come up with, what they reasoned, is that there must be some intrinsic property within the electron, because we know that this describes the complete energy of the orbital should give us one single frequency.
他们想到着一定和，电子的本征性质有关，因为我们知道这个轨道的,完整描述会给出单一的频率。
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These are all one electron atoms, and they are gas, a single atom.
这些都是单电子原子，它们都是气体，都是单原子。
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And resonance is the idea that sometimes one single Lewis structure does not adequately describe the electron configuration around a given molecule, so instead you need to draw two different Lewis structures to describe that more appropriately.
而所谓共振态,就是有时候一个路易斯结构不足以,完整描述一个给定分子的电子排布，因此这时你需要同时画出两个,不同的路易斯结构来描述它,这样会更恰当。
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So I said before when we were talking about single atoms, we always define the zero energy as when an electron was actually ejected, but now, when we talk about chemical reactions taking place, it's very, very rare that we're actually going to be talking about anything that gets to this point here.
我之前说过，当我们讨论单个原子的时候，我们总是把零点能,定在电子被发射出去以后，但是现在，当我们讨论化学反应发生的时候，非常非常罕见出现，确实达到,这种程度的情况。
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N 2 So any chemist should be able to just look at n 2 and know that it's a triple bond, but that's not something that we've learned how did to do yet, so let's go ahead and start a new topic that's going to allow us to have some sort of sense of what the valence electron configuration, which includes whether something's a single or double or a triple bond can be figured out for any given molecule.
任何一个化学家都应该能够仅仅通过看到2,就知道它有一个三键,但是我们还没学习如何做到这点，因此下面我们就开始进入一个新的主题,它将使我们能够有一定的认识,对于价电子的排布情况，包括可以对任何一个给定分子中的键是单键双键,还是三键作出判断。
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But actually there is a little bit of an energy cost into doubling up into a single orbital, because, of course, it takes energy when you create more electron repulsion, that's not something we want to do, but we have to do it here, and it turns out that that effect predominates over, again, the energy that we gain by increasing the atomic number by one.
但实际上，在一个轨道上放两个电子,确实会亏损一点能量，因为，当你加入更多电子，引起更大的排斥能,这显然会消耗能量，这不是我们想要做的，但是在这种情况下我们不得不做，结果这一影响，超过了增加一个,原子序数所得到的能量。
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There is no way that you could irradiate a crystal of nickel with a single beam of x-rays and get that circular ring pattern if the electron beam were behaving as a particle beam only.
没有什么其他的途径,可以让镍晶体发射,单束X光来,继而得到环状图案,如果电子束,是以粒子束形式出现的。
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