• There's a sense of aliveness and energy, and in scientific terms everything is pure energy, so it's not that far-fetched.

    有一种生机和能量,用科学的话来说,万物都是纯粹的能量,因此上面说法也不为过。

    普林斯顿公开课 - 人性课程节选

  • So, in a sense, it says, you know, if you wanted to build a boat that took energy out of the warmth of the air to sail around the world, you can do that.

    因此,某种意义上说,它宣称如果你想要造一艘船,通过从空气中获取热量,这是可以做到的。

    麻省理工公开课 - 热力学与动力学课程节选

  • So, for starters we'll keep that as our zero energy, we're going to change it soon to make something that makes more sense in terms of bonding, but we'll keep that as zero for now.

    因此,首先我们将会保持零点能的这个定义,但很快我们就会对它进行修改,使它在讨论成键时更合理,但是目前我们还是暂时采用这种定义。

    麻省理工公开课 - 化学原理课程节选

  • And that makes sense, too, because the positive three pulling on minus one has a tighter binding energy than positive one pulling on minus one.

    而这也是有意义的,因为+3和-1的相互吸引,产生了比+1和-1的吸引,更强的能量。

    麻省理工公开课 - 固态化学导论课程节选

  • So, when we think about a bond length, this is going to be the length of our bond here, that makes sense because it's going to want to be at that distance that minimizes the energy.

    因此,当我们考虑一个键的长度的时候,这就应该是我们的键长,这是合理的,因为体系会在核间距达到这一距离时,能量到达最小值。

    麻省理工公开课 - 化学原理课程节选

  • So that should make sense, because we saw no energy difference between the actual atoms and the molecules.

    这很好理解,因为我们看到,原子和分子的能量差为零。

    麻省理工公开课 - 化学原理课程节选

  • So it can often make a lot more sense if we think about things in terms of energy.

    通常我们从能量的角度来,考虑就能更好的理解这点。

    麻省理工公开课 - 化学原理课程节选

  • So we know we always want to have our systems in as low an energy as possible, so it makes sense that a bond would happen any time we got a lower energy when we combine two atoms, versus when we keep them separate.

    我们知道我们总是希望使我们的系统,处于能量尽可能低的状态,因此就应该有化学键产生,一旦我们合并两个原子之后体系的能量变得更低,相较于分开时。

    麻省理工公开课 - 化学原理课程节选

  • That makes sense because we're lower in energy, the electrons are now lower in energy.

    这很好理解,因为我们降低了能量,电子能量更低。

    麻省理工公开课 - 化学原理课程节选

  • This intuitively should make a lot of sense, because we know we're trying to minimize electron repulsions to keep things in as low an energy state as possible, so it makes sense that we would put one electron in each orbital first before we double up in any orbital.

    这个直观上讲得通,因为我们知道尝试去最小化电子排斥力,从而尽可能的保持处于一个较低的能态,所以它讲得通,在我们在同一个轨道放入两个电子之前,我们首先把电子放入每一个轨道。

    麻省理工公开课 - 化学原理课程节选

  • So whenever we're thinking about energy states, it's lways more stable to be more low in an energy well, so that's why it makes sense that it's favorable, in fact, to have an electron interacting with the nucleus that stabilizes and lowers the energy of that electron by doing so.

    负的能量越多,能级越低,无论何时,能级总是越低越稳定,所以这就是为什么电子更,倾向于通过和原子核相互作用,来稳定并降低电子的能级。

    麻省理工公开课 - 化学原理课程节选

  • it's an easy calculation -- we're just taking the negative of the binding energy, again that makes sense, because it's this difference in energy here. So what we get is that the binding energy, when it's negative, the ionization energy is 5 . 4 5 times 10 to the negative 19 joules.

    这个计算很简单-我们,只需要取结合能的负值,同样这很容易理解,因为这就是这的能量差,所以我们得到的就是结合能,当它取负值,电离能就是5。45乘以。

    麻省理工公开课 - 化学原理课程节选

  • In some sense, that's one reason to associate this as a kind of energy, H just like mechanical energy u or enthalpy H, it's the minimum free energy state that is the equilibrium state under the relevant conditions.

    在某种意义下,这是我们把这些物理量称为能量的原因,就像机械能U和自由焓,具有最小自由能的状态在特定的条件下,就是平衡态。

    麻省理工公开课 - 热力学与动力学课程节选

  • And it should make sense where we got this from, because we know that the binding energy, if we're talking about a hydrogen atom, what is the binding energy equal to?

    很容易理解,我们怎么得到这个的,因为我们知道,结合能,如果,对氢原子来说,结合能等于什么?

    麻省理工公开课 - 化学原理课程节选

  • And the glitch that doesn't make sense just through periodic trends, is that it turns out that the ionization energy of boron is actually less than the ionization energy up beryllium.

    仅仅考虑周期性规律,是无法理解这个问题的,这里显示硼的电离能,实际上比铍的要小。

    麻省理工公开课 - 化学原理课程节选

  • That makes sense because we're losing energy, we're going to a level lower level, so we can give off that extra in the form of light. And we can actually write the equation for what we would expect the energy for the light to be.

    这很合理,因为我们在损失能量,我们要到一个更低的能级去,我们要以光的形式给出额外的能量,我们可以写下光能量的方程。

    麻省理工公开课 - 化学原理课程节选

  • This should make sense because if something has a low ionization energy, that means it's not very electronegative, which means it's going to be a lot happier giving up electron density, which is essentially what you're doing -- when you're forming covalent bonds is you're sharing some of your electron density.

    这应该是合理的,因为如果某物的电离能很低,这也就意味着它的电负性也不高,那么它就会更愿意,放弃一定的电子密度,而本质上这正是你在,形成共价键时所需要做的,分享你的一些电子密度。

    麻省理工公开课 - 化学原理课程节选

  • So that's just a little bit of a check for yourself, and it should make sense because what you're doing is you're calculating the difference between energy levels, so you just need to flip around which you put first to end up with a positive number here, and that's a little bit of a check that you can do what yourself.

    所以你们总要确保括号,离得这项是正的,这是你们自己,可以做的检查,这事很有道理的,因为你们做的是计算能量差,所以你需要调整顺序来保证一个正数,这是你们自己可以做的检查。

    麻省理工公开课 - 化学原理课程节选

  • So if we say that l is just talking about our kinetic energy part, our rotational kinetic energy, and we know that electrons have potential energy, then it makes sense that l, in fact, can never go higher than n.

    如果我们说,l仅仅是,描述动能项,我们的旋转动能,我们知道,电子有势能,所以可以理解,l不能比n高。

    麻省理工公开课 - 化学原理课程节选

  • So that's why we see the 2 p here, 1206 the 2 s is 12 06, and it makes sense that what we see as the greatest ionization energy, which is also the smallest kinetic energy is that 1 s orbital.

    这就是为什么我们看到,2,p在这里,2,s对应,那么我们看到对应最高的电离能,同时也对应最低的动能的,应该就是,1,s,轨道。

    麻省理工公开课 - 化学原理课程节选

  • So, if, for example, we were looking at a hydrogen atom in the case where we have the n equals 1 state, so the electron is in that ground state, the ionization energy, it makes sense, is going to be the difference between the ground state and the energy it takes to be a free electron.

    电离氢原子所需要的能量,如果我们看n等于1的情况,电子在基态,那电离能,很合理的就是基态,和自由电子态的能量差。

    麻省理工公开课 - 化学原理课程节选

$firstVoiceSent
- 来自原声例句
小调查
请问您想要如何调整此模块?

感谢您的反馈,我们会尽快进行适当修改!
进来说说原因吧 确定
小调查
请问您想要如何调整此模块?

感谢您的反馈,我们会尽快进行适当修改!
进来说说原因吧 确定