And this spin magnetic quantum number we abbreviate as m sub s, so that's to differentiate from m sub l.
这个自旋磁量子数我们把它简写成m下标s,以和m小标l有所区分。
Like, it's harder to get around L.A. because you have to drive everywhere and I really don't like driving.
想要在洛杉矶游玩要比在纽约困难,因为无论去哪都要自己开车,而我确实不喜欢开车。
So here we have 3 minus l equals 0, because it's an s orbital, minus 1, so we have two radial nodes here.
这里我们有3减去l等于0,因为这是s轨道,减去1,我们有两个径向节点。
Let's have a little review of the career of the great poet Orpheus as we get it certainly in L'Allegro and Il Penseroso.
让我们看看伟大诗人俄耳甫斯的经历,这在《快乐的人》和《沉思的人》中都有所提及。
Didn't create a new list. The old l is still there but it's different than it used to be.
它改变了数组,而并没有新建一个数组,老数组l依旧存在。
There's also The L.A. Times, which you can get now online with no problem from the -you can read every day's newspaper.
洛杉矶时报也提过,你可以在网上轻松找到,你可以读到任何时间的报纸
n l m s Once we have chosen a certain mix of n, l, m and s, it is used once for that particular atom.
一旦我们选定了一组量子数,它就只能被一个固定原子所有。
This is a painter called Frans Hals, H-A-L-S.
这是画家法兰斯·霍斯的作品
L.A.'s not as exciting as New York, I guess. It's more suburban and residential than New York.
我认为洛杉矶没有纽约精彩,她更属于郊区,更适宜居住。
It turns out there's a new function strlen S-T-R-L-E-N that you probably have not used yet called strlen, S-T-R-L-E-N, programmers early on and still like to be succinct but communicates sufficiently what they mean.
结果这里有个新的函数,你可能没有使用过,叫做,早期的和现在的程序员喜欢简洁地,但是能充分的传达他们的意思。
STUDENT: PROFESSOR: Oh, I'm sorry. So it's n minus l minus 1.
学生:,教授:不好意思,这是n减去l减去1.
So, you should know that there's four radial nodes, right, we have 5 minus 1 minus l -- is there a question?
你们要记住这里有四个节点,对吧,5减去1减去l,有问题吗?
How many bonding electrons does c l have? All right. Let's see, we've got a mixed response here, it turns out it has two bonding electrons.
氯有多少成键电子?好,让我们来看看,大家的回答不太一致,结果应该是两个成键电子。
And the last example that we're going to talk about is thionyl chloride, so it's s o c l 2. This is another good step forward, because now we actually have four different atoms in our molecule.
我们要讨论的最后一个例子,是氯化亚砜,就是硫,氧,氯,二,这又是一个进步,因为我们的分子中现在有四个不同的原子了。
So I show that here, so in green, you have what's called a carboxcylic acid group, a c o o h, which gets converted by s o c l 2 to a c double bond o c l or an acid chloride.
我在这里用绿色表示,我们所说的羧酸族化合物,碳,氧,氧,氢,它被亚硫酰氯转化为,一个碳氧双键与碳氯单键组成的酰氯。
So when we talk about p orbitals, it's similar to talking about s orbitals, and the difference lies, and now we have a different value for l, so l equals 1 for a p orbital, and we know if we have l equal 1, we can have three different total orbitals that have sub-shell of l equalling 1.
当我们考虑p轨道时,这和s轨道的情形和相似,不同之处在于l的值不一样,对于p轨道,l等于1,我们知道如果l等于1,我们有3个,不同的轨道。
And the first is l, and l is angular momentum quantum number, and it's called that because it dictates the angular momentum that our electron has in our atom.
第一个就是l,l是,角动量量子数,叫它这个名字,是因为它表明,原子中,电子的角动量是多少。
And when we talk about l it is a quantum number, so because it's a quantum number, we know that it can only have discreet values, it can't just be any value we want, it's very specific values.
当我们讲,l是一个量子数时,因为它是量子数,我们知道,它只能去分立的值,它不能取到所有的数,它取一些确定的数。
s We are back over to E as a function of n, l, m and s, only we got there through this other torturous route.
我们回到将E作为函数n,l和,只要我们解决了这个烦人的路径。
So, first, if I point out when l equals 0, when we have an s orbital, what you see is that angular part of the wave function is equal to a constant.
首先,如果l等于0,那就是s轨道,你们可以看到,它波函数的角度部分是一个常数。
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