So for the reversible process, the work done is the integral under the pressure volume state function, the function of state.
对可逆过程,做的功,是压强体积态函数曲线下,的积分面积。
This is just an equality. I have a constant pressure dH process. This term here is equal to zero.
这是一个等式,这是个恒压过程,这项等于零,这意味着。
This is a point that is often confusing, because you can think, well maybe I could calculate what the internal pressure is even for this very rapid process.
这一点可能让你们很困惑,因为你们可以想象这个过程,我也可以计算在这快速的变化中,内部压强是多大。
I could change my external pressure through the whole process, and that's the path.
事实上外界压强,也不必固定。
T2 Is the temperature T2 in this process smaller or larger than if I were to do the process reversibly with the same endpoint pressure.
这里的末态温度,与经过可逆绝热过程,到达相同压强的末态温度相比哪个比较高呢?
If I look at different points in my container during that path, I'm going to have to use a different value of pressure or different value of temperature That's not an equilibrium state, and that process turns out then to be an irreversible process.
如果我要研究在路径中容器里的,不同的点,我就得在容器里不同的点上使用,不同的压强值,或不同的温度值,实际上这不是个平衡态,这个过程是,不可逆过程。
It's nR log of p2 over p1 for the process where there's a pressure change.
结果是dS等于nR乘以p2除以p1的对数,这是对压强变化的结果。
Remember it's the external pressure that's important. In this case, because it's a reversible process, the external pressure turns out to be always the same as the internal pressure.
是过程非常缓慢,比如我把体积,从V1压缩到V2时,我做得十分缓慢,在过程中的任何一点。
Adiabatic q equal to zero. It's also delta H 0 which is zero. The two didn't necessarily follow because remember, delta H is dq so p is only true for a reversible constant pressure process.
在这个过程中ΔH等于,绝热的所以q等于0,而ΔH也等于,这两个也不一定有因果关系,因为,记住,ΔH等于dq只有在恒压。
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