And for a couple of reasons, one this is the first P set where we're actually gonna give you code to work from.
由于一些原因,这里是第一个习题集,在此我们提供了一些代码供大家参考。
Well, presumably because whatever cognitive structures it takes in your brain to underwrite the ability to P-function, those cognitive structures have been broken, so they no longer work.
大概是因为,无论你大脑中的什么认知结构,使得人格功能性成为可能,这种认知结构都被破坏了,它们不再继续工作。
I also want to assume for our present purposes that there's only pressure volume work going on, which is to say I want to put pdV p dV in here minus p dV for dw.
同时假定,对于我们目前的目的而言,只有压强做功这就是说,我要把这里的dw替换为负。
So, it's very easy to calculate, however, the number of radial nodes, and this works not just for s orbitals, but also for p orbitals, or d orbitals, or whatever kind of work of orbitals you want to discuss.
径向节点,的数量,这不仅对s轨道适用,对p轨道,d轨道,或者任何你们想讨论的轨道,都是适用的,它就等于。
So, the work for this process is the integral, pdv or minus the integral, V1, V2, p dV.
此过程中的做功等于负的积分,从v1到v2,外部。
So there's p v work and it's given by the integral minus p external dv or just the integral from one to two of dw.
我们知道对于pv系统来说,功w可以写成黑板上的两种不同形式。
And it's p external and p external is zero, so there's no work.
外部的p是零,所以结果是零,没有做功。
That's equivalent to doing the integral, and so, what we end up getting is that the reversible work v2 pdv is equal to minus integral V1, V2, p dV.
这与刚才的积分过程效果相同,最后,我们得到的结论是可逆过程的功,是负的积分,从v1到。
U It's u, because u is to q plus w right, heat and work, but it's adiabatic. So there's no heat, exchange with the environment, and it's constant volume, so there's no p dV work, right.
什么是零?是U,因为,等于q加w,热量和功,但这是绝热的,所以系统与环境间没有热量交换;,同时它是灯体的,所以也没有pdV形式的功。
V Minus p2, V2. Minus p delta V. So the total work is the work from the left hand side plus the work on the right hand side, p1 V1- p2 V2 which is p1 V1 minus p2 V2.
负p2V2【w=-p2v2】,即负pΔ,所以全部的功就是,左边的功加上右边的功,等于。
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