• Minus p, right? But in fact, if you go back to the van der Waal's equation of state b here's RT over v minus b.

    再减去p,对吗,但是实际上,如果你代回范德瓦尔斯气体的状态方程,这里是RT除以摩尔体积减去。

    麻省理工公开课 - 热力学与动力学课程节选

  • And the useful outcome of all that is that p we get to see how entropy changes with one of those variables in terms of only V, T, and p, which come out of some equation of state.

    这样做的重要结果是,我们得到了熵随着V,T或者,其中一个变量变化的情况,这些可以从状态方程得到。

    麻省理工公开课 - 热力学与动力学课程节选

  • And by state we just mean orbital, so if we're looking at the p orbitals here, x that means that a single electron goes in x, and then it will go in the z orbital before a second one goes in the x orbital.

    我们说的态仅仅意味着轨道,所以如果我们观察这里的p轨道,那意味着单个电子进入,然后它会进入z轨道,在它第二个进入x之前。

    麻省理工公开课 - 化学原理课程节选

  • And it's more dramatic if the system is a gas p T2 V2 p, T2, V2, And let's look at what happens to U these functions of state, to H to u under this transformation.

    如果是气体这个系统,就更具有趣了,让我们看看H和,在这个变化中态函数会发生什么变化。

    麻省理工公开课 - 热力学与动力学课程节选

  • OK, in a few weeks, you're going to find out that we can calculate dH/dp from this equation of state, and you're going to find p out that dH/dp from that equation of state b-a/RT is proportional to b minus a over RT.

    好,在接下来几个星期里,你们将知道从这个状态方程,可以计算出偏H偏p,并且你们会发现,从这个状态方程得到的偏H偏,正比于。

    麻省理工公开课 - 热力学与动力学课程节选

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