So, if we hybridize just these three orbitals, what we're going to end up with is our s p 2 hybrid orbitals.

我们会看到现在有3个未配对的电子，可以成键。

麻省理工公开课 - 化学原理课程节选

And our job is to find out what is the mathematical description of this path, this line in p-V's case that connects these two point.

我们的任务,就是找出，描述这条曲线的方程。

麻省理工公开课 - 热力学与动力学课程节选

sp3 PROFESSOR: OK, so it's 2 s p 3, and our second carbon is also 2 s p 3.

好的，是，第二个碳原子也是2sp3。

麻省理工公开课 - 化学原理课程节选

Problem Set One will be posted on the course's website tonight by 7:00 p.m. It will very clearly walk you through the week's challenges.

习题集1今晚7：00，将在课程的网站上贴出来,它将非常清晰地带领你们,通过这个星期的挑战。

哈佛公开课 - 计算机科学课程节选

So it is very hard to understand P's silence in this regard, if it stems entirely from the post-exilic, priestly circles.

很难理解P资源在这一方面的缄默，如果它来源于流放后时期，牧师圈子。

耶鲁公开课 - 旧约导论课程节选

That's different when you have continuous values-- you don't have P because it's always zero.

和离散型随机变量的分布不同的是,连续型随机变量的分布中,某一点的概率值始终是零

耶鲁公开课 - 金融市场课程节选

p2 It's taking the name p 1 and it's changing its value to point to exactly what p 2 points to.

我要把p1赋值为1,这个操作有什么用呢？,这个操作把p1这个名字的,指针的值改变让它。

麻省理工公开课 - 计算机科学及编程导论课程节选

And there's also,of course,in each one of our cases, there's these higher mental cognitive functions that I've been calling the person functioning, there's the B-functions and there's the P-functions.

当然对我们来说，还有更高级的精神上的认知功能,我称之为人格功能，所以就有生理功能和人格功能。

耶鲁公开课 - 死亡课程节选

Again, so as we don't get confused, normally we use S for strategy, but let's use P since they're prices.

为了避免混淆,通常我们用S表示策略,但是这次我们使用P,因为它代表价格

耶鲁公开课 - 博弈论课程节选

So, let's actually compare the radial probability distribution of p orbitals to what we've already looked at, which are s orbitals, and we'll find that we can get some information out of comparing these graphs.

让我们来比较一下ｐ轨道,和我们看过的,ｓ轨道的径向概率分布，我们发现我们可以通过,比较这些图得到一些信息。

麻省理工公开课 - 化学原理课程节选

It's not constant pressure, because we have a delta p going on. It's not constant volume either.

也不是恒容，这个限制,是这个实验的限制。

麻省理工公开课 - 热力学与动力学课程节选

So it's going to be a sigma bond, 1s and we have oxygen 2 s p 3 and hydrogen 1 s.

它是sigma键，我们有氧2sp3和氢。

麻省理工公开课 - 化学原理课程节选

p Well, it's not just p dS/dV because there's some dS/dV at constant T.

它不是简单的,因为式子中还包含，恒定温度下的。

麻省理工公开课 - 热力学与动力学课程节选

So let's fill it out in this way, 2p keeping in mind that we're going to fill sigma out the pi 2 p's before the sigma.

让我们这样填上去，记住我们先填π,轨道再填。

麻省理工公开课 - 化学原理课程节选

We'll start with talking about the shape, just like we did with the s orbitals, and then move on to those radial probability distributions and compare the radial probability at different radius for p orbital versus an s orbital.

想我们对待ｓ轨道那样，我们先讨论ｐ轨道的形状，然后是径向概率密度分布,并且把ｓ轨道和ｐ轨道在,不同半径处的径向概率做一个比较。

麻省理工公开课 - 化学原理课程节选

s 2 2 s 2 2 p 6 This has the electron configuration of 1 s 2, 2 s 2, and 2 p 6.

它的电子排布是。

麻省理工公开课 - 化学原理课程节选