p2 One of them is going to end up at pressure p2 p3 and the other is going to end up at pressure p3.
其中一种末态压强为2,另一种末态压强为。
p2 So they're both p2. external is p2 p2 V2 T2 and I have p2, V2, T2, on the other side.
都是2,这样末态是。
p1 But if I say, are p 1 and p 2 the same point, it says yes.
和p2是不是同一个点,It,says,no。,返回的结果是肯定的,在这里我有个要强调的点,这个例子里发生的是。
So they're going to P1, will the price of Firm 1, and P2 will be the price of Firm 2.
所以P1代表,公司1的价格,而P2代表公司2的价格
and when we remove one of the weights, p2 this gives an external pressure p2.
外部压强,变为。
p1 V1 Initial find -- there are many ways p2 V2 V1 I can get from one state to the other.
初态的氩气状态为,末态为。
There's p1 here, and p2 here So I'm starting at p1, V1. I'm starting right here And I'm going to end right here.
它的分子间作用力很小,十分接近理想气体,对它做一个压缩过程。
So now, instead of having p external p2 equals to p2 here, I put p1 and I let this whole thing go reversibly.
也就是说,现在开始的外界压强不是,而是p1,整个过程都是可逆的。
p2 It's taking the name p 1 and it's changing its value to point to exactly what p 2 points to.
我要把p1赋值为1,这个操作有什么用呢?,这个操作把p1这个名字的,指针的值改变让它。
Every time you do the experiment T in equilibrium with the heat bath at T, v2 you'll get the same p2 and V2.
与热库相接触的每次实验中,达到热平衡后的温度都是,压强都是p2,体积都是。
p2/p1 Then I'm going to get, be left with a p2 over p1.
于是右边剩下。
Then you take p1 to p2 with V constant.
图上画出来就是这样。
p2 It would stop there because we've chosen p2.
因为我们选的压强是。
I take V1 to V2 first, keeping the pressure constant at p1, then I take p1 to p2 keeping the volume constant V2 at V2. Let's call this path 1.
容易计算的路径,第一条路径,是首先保持压强不变,体积从V1压缩到。
p2 p1 is greater than p2. Then I want to reverse direction of time. I want the arrow of time to go so that the gas goes from p2 to p1.
一直推,一直推,p1大于,接下来我想让时间倒流,让气体从p2到p1。p2比p1小。
I'm going to say, gee, p2 is the x value the same in both of them, and if it is, and the y value's the same, then this is the same point, I'm going to return true.
这样的数据对象,我会把它们命名为p1和,我会去查看,看看两个对象中,的x值是不是相同,如果相同的话,就去查看y值是否相同。
It's nR log of p2 over p1 for the process where there's a pressure change.
结果是dS等于nR乘以p2除以p1的对数,这是对压强变化的结果。
So on the p-V diagram, then, V1 V2 p1 p2 there's a V1 here a V2 here, a p1 here a p2 here.
在p-V图上,这是。
I've got another little thing here that I'm going to use a little later on that just prints out values of things.
给我p2的x值,对它们进行比较,就像我们通常会做的那样。
If P2 is actually above the monopoly price, then what's my best response in that case?
如果P2真的高于垄断价格,我的最佳对策是什么
And so, we can rewrite this as the work nRTln is equal to minus nRT log p1 over p2, nRTln or nRT log p2 over p1.
因此我们可以把这个式子改写一下,功等于负的,或者。
This is a positive number, p1 is smaller than p2.
这就是系统对外界做的功。
OK, we're going to do this reversibly, which means we're going to slowly change the external pressure very, very slightly at a time, so that at every point we're basically in equilibrium, p2/ until the pressure reaches a new smaller pressure p2.
整个过程保持可逆,外界压强,变化得很慢,每一个瞬间,都保持平衡,直到压强减小到末态值。
p2 I'm going to set that equal to p2.
现在外界压强为。
so we know how to do this, and we know this thing when it hit these stops, v2 the pressure with p2, and the volume was V2.
所以我们知道怎么计算,当活塞到达这两个挡板时,压强是p2,体积是。
p2 There is going to be an internal pressure where T1 p1 is less than p2 and there's V1 and T1 here.
内部气体压强p1小于,体积为V1,温度为。
p1 And p2 is less than p1, 1 so this number right here is less than 1.
由于p2小于,这个数小于。
p1V1/R That p2 V2 over R, and then I have p1 V1 over R, the R's cancel out.
就是p2V2/R除以,两个R消掉了。
And I'll give it an x value of 3 3 and a y value of 4.
一个笛卡尔坐标3,然后给p2的x坐标赋值为。
External pressure is p3. It's higher than p2.
外部压强为p3,比p2大。
应用推荐