If n is greater than zero, I decided I would say, "You picked a positive number, backslash n," so put the cursor on the next line, else if n was not less than zero, I say, "You picked a negative number, backslash n."
如果n比0大,我就决定来说:,“你选择了一个整数,反斜杠n“,所以你把光标,放在下一行,另外如果n不小于0,我说:,“你选择一个负数,反斜杠n“
So, what we're saying is that we have n equals to 4, and m sub I being equal to negative 2.
我们说的是n等于4,ml等于-2
All the energies are negative because it is a bound system. I start up here with n equals one.
所有能量级都是负数,因为它是一个束缚系统,在这里我从n等于1讲起。
Negative 1 plus 0 should add up to negative 1, if in fact, we're correct for the c n anion.
负一加上零应该等于负一,如果是这样,我们对于氰离子的结果就是正确的。
So, if we think about the second case here where we have c n minus, now we're talking about a molecule with a net charge of negative 1.
那么,如果我们考虑的是第二个例子,也就是氰离子,那么现在我们讨论的是一个净电荷量为负一的分子。
PROFESSOR: OK. We can have n 4, l 3, and then, sure, we can have m sub l equal negative 2 if l equals 3 What's the second value of l that we can have?
教授:嗯,我们有n4,l3,然后我们有ml等于-2,如果l等于3,l可以有的第二个值是多少?
n And these are known as anions. It has the n, which might conjure up negative, or anion and minus both have five letters.
这些就是负离子,有,能让我们想起,负,这个字,或者负离子和负号都是5个字母。
So now we have that energy is equal to the negative of the Rydberg constant divided by n squared.
我们可以把能量方程大大简化,现在能量等于负的Rydberg常数除以n平方。
So instead of being equal to negative z squared, now we're equal to negative z effective squared times r h all over n squared.
这里不再等于-z的平方,现在我们等于-有效的z的平方,乘以RH除以n的平方。
n l So negative e, which is sub n l, because it's a function of n and l in terms of quantum numbers.
也就是负的,E,下标是,因为它是一个,关于量子数,n,和,l,的函数。
And that's going to be equal to negative z effective squared times r h over n squared.
有效的z的平方,乘以RH除以n的平方。
ml=-2 So let's say we have n equals 4, and n sub l equalling negative 2.
这里n等于。
So we know that we can relate to z effective to the actual energy level of each of those orbitals, and we can do that using this equation here where it's negative z effective squared r h over n squared, we're going to see that again and again.
我们知道我们可以将有效电荷量与,每个轨道的实际能级联系起来,我们可以使用方程去解它,乘以RH除以n的平方,它等于负的有效电荷量的平方,我们将会一次又一次的看到它。
So, it's negative Rydberg constant over n squared.
它等于负的Rydberg常数,除以n平方。
We're going to get to more complicated atoms eventually where we're going to have more than one electron in it, but when we're talking about a single electron atom, we know that the binding energy is equal to the negative of the Rydberg constant over n squared, so it's only depends on n.
我们以后会讲到,更加复杂的情况,那时候,不只有一个原子,但当我们讲,单个原子的时候,我们知道结合能,等于,负的Rydberg常数,除以n平方,所以它仅仅由n决定的。
We also know how to figure out the energy of this orbital, and we know how to figure out the energy using this formula here, which was the binding energy, -Rh which is negative r h, we can plug it in because n equals 1, so over 1 squared, and the actual energy is here.
我们知道如何算出,这个轨道的能级,而且我们知道如何,用这个公式,算出能量,也即是结合能,等于,我们把n等于1代进来,所以除以1的平方,这就是能量。
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