• So, what we have left in our equation is only one part that n we haven't explained yet, and that is that n value.

    现在方程里只剩下一个常数,我们还没有解释,这就是。

    麻省理工公开课 - 化学原理课程节选

  • And again, our energy is going to be the same where we again only depend on the n value.

    同样的能量,和以前一样,因为它,只决定于n的值。

    麻省理工公开课 - 化学原理课程节选

  • OK. What does that say? I'm going to change MinIndex min index to also point there n value is 8, j starts off here, and I say, OK, is the thing I'm looking at here smaller than that? Yes.

    好的,这意味着什么?,我打算交换,让它也指向那里,MinVal是8,j从这里开始,我要找的值比这个小么?是的。

    麻省理工公开课 - 计算机科学及编程导论课程节选

  • I declare a variable called n. I'm not giving it a value yet, so I had better be careful.

    我申明一个变量n,我先不给它赋值,所以我最好小心点。

    哈佛公开课 - 计算机科学课程节选

  • We go to n equals two for a fixed value of Z.

    我们对于一个给定的Z值,让n等于。

    麻省理工公开课 - 固态化学导论课程节选

  • And I want to really highlight here we're talking about for a hydrogen atom orbitals - with the same n value have the same energy.

    我想强调的是,我们所说的,都是对单个的氢原子,和言的,对于同样的n值能量相同。

    麻省理工公开课 - 化学原理课程节选

  • Again, the reason for that is because the energy only depends on the n value here, it doesn't depend on l or on m.

    因为,能量,只和n的值有关,与l和m的值无关。

    麻省理工公开课 - 化学原理课程节选

  • So if we're keeping n the same, we look and what we saw was that size actually decreases as we increase the value of l.

    如果我们保持n不变,我们看到随着l值的,增大尺寸变小。

    麻省理工公开课 - 化学原理课程节选

  • If we have n equals 4, what is the highest value of l that we can have?

    如果n等于4,l的最大值是多少?

    麻省理工公开课 - 化学原理课程节选

  • Ah, n times, because for each value of i, I'm going to do that m thing, n*m so that is, close to what you said, right?

    因此这就和你说的差不多了对不对?,这个问题的复杂度为,让我写下来,是-对不对,是?

    麻省理工公开课 - 计算机科学及编程导论课程节选

  • We knew from Friday, when we talked about energy, that ground state was that n equals 1 value, that was the lowest energy, that was the most stable place for the electron.

    我们上周五知道了,在讨论能量的时候,基态指,n等于1的态,它能量最低,是,最稳定的态。

    麻省理工公开课 - 化学原理课程节选

  • So, our next level up that we can go is going to be the n equals 2 energy level, but we also have an l and an m value, 0 so our lowest l is going to be a there.

    所以下一个能量,是n等于2的能级,但我们还有l和m的值,所以我们最低的l等于。

    麻省理工公开课 - 化学原理课程节选

  • So if we say that we have a 2 p orbital here, that means that we can have 2 how many different complete orbitals have a 2 for an n, and a p as its l value? three.

    如果我们说这里有一个“2p“轨道,那就意味着我们有,多少完全不同的轨道对于n有一个,而且对于l值有一个p?3个。

    麻省理工公开课 - 化学原理课程节选

  • And unlike n, l can start all the way down at 0, and it increases by integer value, so we go 1, 2, 3, and all the way up.

    不像n,l可以从0开始取,然后每次增加一个整数,所以我们可以去1,2,3,一直下去。

    麻省理工公开课 - 化学原理课程节选

  • This should make sense to you, because they don't, in fact, want to gain another electron, because that would mean that electron would have to go into a new value of n, a new shell, and that's really going to increase the energy of the system.

    这对大家来说应该容易理解,因为它们实际上不想得到另一个电子,因为这意味着这个电子不得不,到一个新的,n,值更大的壳层上去,这将会增加系统的能量。

    麻省理工公开课 - 化学原理课程节选

  • But also unlike n, l cannot have just any value, we can't go into infinity.

    但不像n,l,不能取所有整数,不能到正无穷。

    麻省理工公开课 - 化学原理课程节选

  • Core electrons are all those electrons held in really tight with the nucleus in the inner shells, whereas the valence electrons are only those electrons that are in the outer-most shell, or at your highest value of n of the principal quantum number.

    芯电子是那些,在内壳层被原子核束缚得非常紧的电子,而价电子只包括,最外层的电子,或者说主量子数,n,的值最大的那些电子。

    麻省理工公开课 - 化学原理课程节选

  • This first number here gives the value of n.

    这里的第一个数字是n的值。

    麻省理工公开课 - 固态化学导论课程节选

  • That's why in the earlier models of the atom, they're not horrible to sometimes think about just each n value as a little ring around.

    这就是为什么在早期原子模型中,人们没有感觉到把每一个,n,都想象成,一个绕核的小圆圈有什么不妥。

    麻省理工公开课 - 化学原理课程节选

  • So what's our value for n here?

    是的对的?

    麻省理工公开课 - 化学原理课程节选

  • to the n, every value in the 1 bit vector we looked at last time is either 0 or 1. So it's a binary n number of n bits, 2 to the n.

    从2到n,我们上次看到的,位向量的每个值不是0就是,所以它是n,比特的二进制数,从2到。

    麻省理工公开课 - 计算机科学及编程导论课程节选

  • The other main difference that we're really going to get to today is that in multi-electron atoms, orbital energies depend not just on the shell, which is what we saw before, not just on the value of n, but also on the angular momentum quantum l number. So they also depend on the sub-shell or l.

    我们今天要讨论的,另一个很重要的区别就是,在多电子原子中,轨道能力不仅仅依赖于,我们以前看到的外层,不仅仅依赖于n的值,而是与角动量量子数也有关系,所以它们也依赖于亚外层或者。

    麻省理工公开课 - 化学原理课程节选

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