• But what's important is not where that most probable radius is when we're talking about the z effective it feels, what's more important is how close the electron actually can get the nucleus.

    但重要的不是,最可能半径,当我们谈论它感到的有效电荷量的时候,更重要的是,电子实际上。

    麻省理工公开课 - 化学原理课程节选

  • For example, when we're talking about radial probability distributions, the most probable radius is closer into the nucleus than it is for the s orbital.

    举例来说当我们讨论径向概率分布时,距离原子核最可能的半径是,比s轨道半径,更近的可以离原子核有多近。

    麻省理工公开课 - 化学原理课程节选

  • So, I want to contrast that with another concept that seemed to be opposing ideas, and that is thinking about not how far away the most probable radius is, but thinking about how close an electron can get to the nucleus if it's actually in that orbital.

    我要将它和另外一个,看起来相反的概念相比较,我们不是考虑,最可能半径离原子核有多远,而是考虑如果电子在那个轨道上,能多接近原子核。

    麻省理工公开课 - 化学原理课程节选

  • The other thing that I want you to notice, is if you look at the most probable radius, for the 2 s orbital it's actually out further away from the nucleus than it is for the 2 p orbital.

    另外一个你们要注意的地方就是,如果你们看它的最可能半径,2s轨道比2p轨道的,要更加远离原子核。

    麻省理工公开课 - 化学原理课程节选

  • So again, what we see is the same pattern where the most probable radius, if we talk about it in terms of the d, that's going to be smaller then for the p, and the 3 p most probable radius is going to be closer to the nucleus than it is for the 3 s most probable radius that we're looking at.

    同样的,我们可以看到相同的行为,d轨道的,最可能半径,比p轨道小,3p轨道的,最可能半径,比3s轨道离原子核更近。

    麻省理工公开课 - 化学原理课程节选

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