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In this case here, our property is the value of the pressure times the volume, times the molar volume. That's the property.
或者电阻,对气体来说，它的特性是气体压强。
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So for the reversible process, the work done is the integral under the pressure volume state function, the function of state.
对可逆过程，做的功,是压强体积态函数曲线下，的积分面积。
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If we have too much gas in here, in other words, if the gas is at too high a pressure, the collisions with the gas molecules will consume the energy of the electrons and, again, we will see nothing.
假设这里有过多气体，换句话说，如果气体处在一个高压状态下，气体分子间的碰撞将会消耗,电子的能量，同样，什么也没有。
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Mr. Trichet thinks that the Fed is running dangerous inflation risks ." by cutting rates too soon in the face of Wall Street pressure."
特里谢认为,美联储降息过快,将面临来自华尔街的压力而最终身陷囹圄“
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The partial pressure of the water, of gaseous water above that equilibrium of ice and water is not one bar, it's much less.
哪里错了吗？,问题在于,冰水混合物上方的,大气中水蒸气的分压，不是一个大气压。
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And the equation of state, pressure versus volume at constant temperature, is going to have some form, let's just draw it in there like that.
系统的态函数，恒温下压强比体积，变化曲线，就像这样。
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So, all I want to do now is look at the derivatives of the free energies with respect to temperature and volume and pressure.
我现在所要做的一切就是,考察自由能对,温度，体积和压强的偏导数。
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And our heat of reaction or enthalpy of reaction is defined as the enthalpy at constant pressure.
我们的反应热，或反映,的焓被定义为恒压，等温。
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How many moles of gas are there in each case, in reactants and products? If that changes, of course you know that the pressure in there is going to change at constant volume if the amount of gas in there is changing.
在反应物和生成物中，各有多少摩尔的气体？,如果它发生了变化,当然在等体条件下，如果气体的总量,发生了变化，压强也会发生变化。
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What we define as zero is the enthalpy of every element in its natural state at room temperature and ambient pressure.
我们将零点定义为每种元素,在室温和正常大气压下,在其自然状态下的焓。
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p2 One of them is going to end up at pressure p2 p3 and the other is going to end up at pressure p3.
其中一种末态压强为2,另一种末态压强为。
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This piston is being brought out, so we expect 0 the work to be negative, negative. And we start o V2 ut with zero volume. We end up with a volume p2 of V2, and the external pressure is constant to p2.
所以我们可以想象功是负的,开始的时候体积是,最终的容积是,外界的压力恒为。
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This is very different from the functions of state like pressure and temperature.
联系初末两态的整个过程,这与压强。
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Pressure is when you have one of these hard spheres colliding against the wall.
这是一个小球,它与墙发生碰撞。
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Pressure has dropped out of the picture completely here. So there is no p dependence here.
理想气体的H只是温度的函数,这对于真实气体来说是。
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And the triple point of water is 16K that temperature and pressure - there's a unique temperature and pressure where water exists in equilibrium between the liquid phase, the vapor phase, and the solid phase.
与水的三相点,我们定义它为273。,水的三相点,是一个特定的温度和压强,可以使水的液态，气态和固态三相共同达到平衡，三相点是液态。
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