And one thing I want to tell you to start out with is something about this c h 3 group here.
有一点需要告诉大家的是,从这个一个碳原子和三个氢原子的组合开始。
It turns out after you do all the math, H it turns out to be delta H equals zero.
要等你做完所有的计算之后,才能知道结果,结果证明Δ
H And, by the way, if you do this for the hydrogen, H it ought to come out the same.
顺便说一句,如果是,或者如果是。
The bond, it turns out, 5° is 104 . 5 degrees, that h o h bond.
这个键即,HOH键角,是104。
What I want to point out also is that this h hat, the Hamiltonian operator written out for the simplest case we can even imagine, which is a hydrogen atom where we only have one electron that we're dealing with, and of course, one nucleus.
我也想指出的是,我们能想到的最简单情况,的哈密顿算符,是一个只有一个电子,也只有一个原子核的氢原子。
So we can figure out the energy of each photon emitted by our UV lamp by saying e is equal to h c over wavelength.
所以我们可以计算出,每个从紫外光源射出的光子,也就是e等于h乘以c除以波长。
Therefore, from experiments, u is only a function of temperature for an ideal gas, H and therefore from these experiments, 0 we come out with delta H dH/dp is equal to zero.
因此,从实验可以得出,对于理想气体u只是温度的态函数,因此从这些实验中我们得到Δ,偏H偏p等于。
So what actually turns out the reality is that h e 2 does exist, but it exists as the weakest chemical bond known, and it wasn't, in fact, even found to exist until 1993, so I can assure you this is not a bond that you see very often in nature, and it is a very, very weak bond.
实际上He2键是存在的,但它是目前所知的最弱的键,直到1993年它才被发现,所以我可以向你们保证在,自然界你们不可能经常看到它,它是种非常非常弱得键。
Now, before, of course, in the first part of the class u we started out looking at u H and then looking at H not as functions of S and V or S and p, but as functions of temperature, mostly.
现在,在本课的前一部分,我们首先讨论了,然后讨论了,这两个量并未写成S和V或者S和p的函数,而是写成了温度的函数。
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