So, we see that the two h atoms separate have a certain energy that's lower than when the electron's not with the atom.
那么,我们看到两个分开的氢原子所具有的能量,比原子中没有电子时更低。
So, I just want to write a few examples down with a few values for delta u or delta H or delta S, and see whether we can get any clues from what we see.
我先写一些例子,例子包含一些内能,自由焓和熵的变化数值,然后看从中,我们能不能得到一些启示。
H2 So the simplest case we can think of is with h 2 where we have two unpaired electrons, each in a 1 s orbital of a separate h atom.
最容易想到的例子是2,我们有两个未配对电子,每个都在一个分开的1s轨道上。
Well, we would have to H+ have one of these hydrogen atoms go to an H plus, * plus an electron, right? **H --> H+ + e-** So, now we have a hydrogen ion here.
我们先要让,一个氢原子变成氢离子,加上一个电子,对么*,我们现在有一个氢离子了。
In a .h file, it's generally the names of functions other people wrote.
在头文件里,只有一些函数名。
This is a painter called Frans Hals, H-A-L-S.
这是画家法兰斯·霍斯的作品
Therefore, from experiments, u is only a function of temperature for an ideal gas, H and therefore from these experiments, 0 we come out with delta H dH/dp is equal to zero.
因此,从实验可以得出,对于理想气体u只是温度的态函数,因此从这些实验中我们得到Δ,偏H偏p等于。
The more important thing that I want you to notice when you're looking at this wave equation for a 1 s h atom, is the fact that if you look at the angular component of the wave function, you'll notice that it's a constant.
我要你们注意的,更重要的一点是,当你们看到,这个氢原子1s轨道方程的时候,如果你们看,波函数,的角向部分,你们会发现它是一个常数。
So notice a difference in these structures, is this has an n h bond whereas this has an o h bond.
注意它们之间的有一点不同,那就是一个有氮氢键,而另一个有氧氢键。
So, for example, down here I wrote that it was n 2 and that it was h 2, but when I re-wrote the molecules up here, you saw that it's an h h single bond where it's a nitrogen-nitrogen triple bond.
比如,在这下面我写的是氮分子2,而这个是氢分子,但我在上面把这些分子的形式改写了,大家可以看到,这是一个氢与氢之间的单键,含一个氮与氮之间的三键。
It is underpopulated right now, so if you are still shopping for a humanities subject, this one bears the precious CI-H designation.
现在它们的选课人数比较少,如果你们还需要一门人文学科,这些都是很可贵的沟通密集型课程。
So what we'll have here is a trigonal planar case, and you can see that we only have three electrons that are set for bonding, so we'll add three hydrogens, and for b h 3, we'll get a stable structure here.
让电子劲量远离的时候,不用考虑它,这个例子是平面三角形,你可以看到,只有3个电子可以成键。
include cs50 h But this says include and this says include a file called cs50.h that lives in some special place on the server that the cs50 staff wrote.
这里写在,众所周知,cs50,h是由CS50的员工,编写的一个库文件。
So now we have a different sign for delta H and it still happens spontaneously.
现在自由焓的变化的符号不一样了,但是这个过程仍然自发的进行。
And if you work out the energetics as we've gone with thermochemistry, dH you discover there's a huge negative delta H.
如果你计算能量变化,就像在化学热力学中所作的一样,你会发现很大的负的。
H for an ideal gas is only a function of temperature. This is not true for a real gas fortunately, but it's true for an ideal gas.
不正确的,但是幸运的是,对于理想气体是完全正确的。
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