And the bigger lesson from that is that entropy, unlike energy u or enthalpy H, we could define an absolutely number for it.
热力学第三定律的一个更重要的推论是,与内能和自由焓不同,我们可以给上定义一个绝对的数值。
How do we go from that experiment to H the terms that we're trying to get, these slopes.
我们怎样从实验得到我们想要的量?,记住,我们想要得到Δ
Well, the energy of the photon, hv we know from Planck, is h nu, which is hc over lambda.
好吧,光子,我们从普朗克那得知,它是,即hc/lambda,波长。
So, if we talk about dissociating h 2, we're going from the h 2 molecule, and breaking this bond right in half, so we now have two individual hydrogen atoms here.
那么,如果我们讨论的是离解氢分子,我们将从氢分子开始,使这个键断裂,一分为二,那么就得到了两个分开的氢原子。
So most scholars think that that block of material comes from a different priestly school, and so we designate that H: holiness.
因此大部分学者认为这一部分内容,出自不同的祭司学派,我们用H来代表“神圣“
So, I just want to write a few examples down with a few values for delta u or delta H or delta S, and see whether we can get any clues from what we see.
我先写一些例子,例子包含一些内能,自由焓和熵的变化数值,然后看从中,我们能不能得到一些启示。
So in principle, if I measure how much hotter, I can determine how much heat was produced, and from that, I should be able H to calculate delta H at T1.
所以原则上,如果我测量,变热了多少,我就能确定,有多少热被产生,从中我就可以计算T1下的Δ
Therefore, from experiments, u is only a function of temperature for an ideal gas, H and therefore from these experiments, 0 we come out with delta H dH/dp is equal to zero.
因此,从实验可以得出,对于理想气体u只是温度的态函数,因此从这些实验中我们得到Δ,偏H偏p等于。
So, we can get from these energy differences to frequency h by frequency is equal to r sub h over Planck's constant 1 times 1 over n final squared minus 1 over n initial squared.
所以我们通过不同能量,得到不同频率,频率等于R下标,除以普朗克常数乘以1除以n末的平方减去。
This is why people right tables and tables of H delta H's. Why you have delta H's from all these reactions, because this is basically the heat and the heat is something we can measure, we can control. We can figure out how much heat is going in and out of something.
这就是为什么人们一再提出ΔH的原因,为什么在所有的反应中你都能看到Δ,因为它就是热量,而且热量,是一种我们可以测量并且控制的东西,我们可以测量出有多少热量,从一些东西里面放出或被吸收。
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