Same bond, symmetric bonds means equal energy, which means equal links.
相同的对称的化学键意味着相等的能量,相同的联系。
And the word degenerate simply means same energy, are of equal energy when they're degenerate.
简并“一词指的是,能量相同,你有n平方个等能轨道,是简并的。
I have four bonds that are of equal energy, and he called this an sp3 hybrid.
我已经将4个能量相等的键画好了,他把这称为sp3杂化。
One is, du, u is called the internal energy dw or just the energy, is equal to dq plus dw.
其中一个是:du,u是内能,或能量,等于dq加上。
That means our energy is equal to 6.626 times 10 to the -34 joules times seconds.
这意味着能量等于,6,626乘以10的-34次方焦耳每秒。
Our ionization energy is going to be equal to the incident energy coming in, minus the kinetic energy of the electron.
我们的电离能将等于,入射能量,减去电子的动能。
So what we're saying here is the incident energy, so the energy coming in, is just equal to the minimum energy that's required to eject an electron.
这里我们来讨论一下,入射能量正好等于,发射出一个电子所需要的最低能量的情况。
And if we experimentally know z what the ionization energy is, we actually have a way to find out what the z effective will be equal to.
我们实际上就有了一个办法,去找出有效的,等于多少,我们可以使用这里的方程。
That is going to equal the energy of the electrons in H2 minus the energies of the electrons in H.
这等于H2分子的能量2,减去H原子中电子的能量。
But he said the energy of an X-Y bond is going to be equal to the square root.
但他说XY键的键能,会等于XX键与YY键键能乘积的平方根。
So, we do this here for the photoelectric effect, and in terms of the photoelectric effect, what we know the important point is that the incoming photon has to be equal or greater in energy then the work function of the metal.
所以,我们做这个是为了说明,光电效应,在光电效应方面,我们知道的最重要的事情,就是入射的光子能量必须等于,或者大于金属的功函数。
It is essentially equal to internal energy for condensed systems, but when you look in the books sometimes they will use this term.
它与内能是相同的,在凝聚体系中,在你看书时有时你会发现,它们会这样使用。
So, another way to talk about dissociation energy is simply to call it bond strength, it's the same thing, they're equal to each other.
讨论离解能的另外一种方式,是直接称它为键的强度,它们是一样的,彼此相等。
We have discovered that this partial derivative that appears in the definition, the abstract definition of the differential for internal energy, is just equal to the constant volume heat capacity.
我们还发现,这个偏微分出现在了,内能的偏微分,定义式中,它也就是热容。
So now we have that energy is equal to the negative of the Rydberg constant divided by n squared.
我们可以把能量方程大大简化,现在能量等于负的Rydberg常数除以n平方。
And that's going to be equal to the negative the binding energy of 2 s in b, in neutral boron.
它应该等于中性硼原子中,2,s,电子的束缚能的负值。
So, if we start instead with talking about the energy levels, we can relate these to frequency, because we already said that frequency is related to, or it's equal to the initial energy level here minus the final energy level there over Planck's constant to get us to frequency.
如果我们从讨论能级开始,我们可以联系到频率上,因为我们说过频率和能量相关,或者说等于初始能量,减去末态能量除以普朗克常数。
So we can figure out the energy of each photon emitted by our UV lamp by saying e is equal to h c over wavelength.
所以我们可以计算出,每个从紫外光源射出的光子,也就是e等于h乘以c除以波长。
So, therefore, we can rewrite our equation in two ways. One is just talking about it in terms only of energy where our kinetic energy here is going to be equal to the total energy going in -- the energy initial minus this energy of the work function here.
所以我们可以把方程,写成两种形式,一个是,只考虑能量,动能等于总的,入射能量-初始能量减去,功函数的能量,我们如果想解决,比方说,我们想知道。
We've got a lot of constants in this solution to the hydrogen atom, and we know what most of these mean. But remember that this whole term in green here is what is going to be equal to that binding energy between the nucleus of a hydrogen atom and the electron.
在这个解中有很多常数,其中大部分我们,都知道它们代表的意思,但记住是这整个绿色的部分,等于核子和电子的结合能。
So, we were talking, however, about energy in terms of electron affinity, so we can actually relate electron affinity to any reaction by saying if we have this reaction written as here where we're gaining an electron, we say that electron affinity is just equal to the negative of that change in energy.
但是,我们现在讨论的能量,是电子亲和能,因,此我们可以将电子亲和能,与任何反应联系起来,只要我们将反应写成这种得到电子的形式,我们说电子亲和能就等于,反应前后能量变化的负值。
we start high and go low, we're dealing with emission where we have excess energy that the electron's giving off, and that energy is going to be equal the energy of the photon that is released and, of course, through our equations we know how to get from energy to frequency or to wavelength of the photon.
当我们从高到低时,我们说的,是发射,电子有多余的能量给出,这个能量等于,发出,光子的能量,当然我们可以通过方程,从能量知道,光子的频率,和波长。
And we know that n describes the total energy, that total binding energy of the electron, so the total energy is going to be equal to potential energy plus kinetic energy.
我们知道,n是描述总能量的,电子总的结合能,所以总能量,等于,势能加动能。
Then we would be able to change our equation to make it a little bit more specific and say that delta energy here is equal to energy of n equals 6, minus the energy of the n equals 2 state.
第一激发态,我们就可以把方程,变得更具体一点,能量差,等于n等于6能量,减去n等于2的能量。
And we wrote something that looks, the energy is equal to minus the Madelung constant times Avogadro's number, 0R0 q1 q2 over 4 pi epsilon zero R zero.
我们写下了,晶格能等于负的马德隆常数,乘以阿伏伽德罗常数,乘以q1q2除以4πε
And we know what that's equal to, this is something we've been over and over, ionization energy is simply equal to the negative of the binding energy.
而且你知道它等于什么,这是我们说过一遍又一遍的,电离能就等于,负的束缚能。
And it should make sense where we got this from, because we know that the binding energy, if we're talking about a hydrogen atom, what is the binding energy equal to?
很容易理解,我们怎么得到这个的,因为我们知道,结合能,如果,对氢原子来说,结合能等于什么?
We can also talk about it in terms of if we want to solve, if we, for example, we want to find out what that initial energy was, we can just rearrange our equation, or we can look at this here where the initial energy is equal to kinetic energy plus the work function.
初始能量是多少,也可以,写成另一种形式,我们可以把方程变形,或者我们看这里,初始能量等于,动能加功函数。
We can also figure out the energy of this orbital here, and the energy is equal to the Rydberg constant.
我们同样可以知道,这个轨道的能量,它等于,Rydberg常数。
So, the very important conclusion that nu Einstein made here is that energy is equal to nu h times nu, or that h times nu is an actual energy term.
做出的重要结论就是能量,等于h乘以,或者说h乘以,是一个能量项。
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