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But in this case it's a response produced in the negative register similar to the responses produced in the saloon.
在这次让人讨厌的举动中,理查表现得与在酒吧里一样。
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And in this case, the tie-breaker goes to the molecule in which the negative charge is on the most electronegative atom.
而在这种情况下，我们需要进行“附加赛“,也就是看看分子中带有负的,形式电荷的原子是不是电负性最高的。
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So if delta v is negative, in this case delta v is negative, OK, delta v is negative, pressure is a positive number, negative times negative is positive, work is greater than zero.
也就是当活塞,压缩气体的时候，做的功是正的，按照这一规定,我们需要在这里，加上一个负号，这是习惯规定。
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So, in this case, we see that our formal charge is negative on the nitrogen, in this case it's negative on oxygen.
那么，在这种情况下，我们看到氮的形式电荷是负的，而在这种情况下，氧的是负的。
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So let's look at a case where it's actually going to be negative.
那么让我们来看一个它是负值的例子。
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We will never have a case where ionization energy is negative.
我们绝不会见到一个,电离能是负值的情况。
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And if we do that calculation, what we find out is that the binding energy, in this case where we have no shielding, 72× is negative 8 . 7 2 times 10 to So, let's compare what we've just seen as our two extremes.
我们会发现结合，能在这个情况中，没有屏蔽，等于-8。,所以我们来对比一下,我们在两个极端的案例中看到了什么。
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Often a good thing to start with is to put the lowest ionization energy atom in the middle, and if you don't have charge separation then go with that structure, but if you do find you have a lot of separation, such as the case in negative 2, positive 2, and minus 1, then you want to say wait a second, this is really bad in terms of formal charge, let me go ahead and see what other options I have here.
通常一开始把电离能最低的原子,放在中心位置就很好了，如果你发现电荷没有分开,那么这个结构就没问题了，但是如果你发现有很多分开的电荷，比如这种情况，有负二，正二和负一，那么你会想要说等一下，从形式电荷来看这很不好，让我去看看其它可能的选择。
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Now if you're at the temperature which is b higher than the inversion temperature, in that case here, a over RT is small compared to b, and this is going to turn out to be negative.
T>Tinv】,这时a/bR小于,结果是负数，因此如果温度。
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