So what I want to point out is that it creates an effect that is exactly opposite of a bond.
我要指出的是,它造成的效果和成键正好相反。
It's much more relevant to set our zero point energy as the separation of a bond in terms of talking about the reactions that we'll usually be dealing with here.
更好的是把零点能定在,键断裂的时刻,在讨论化学反应的时候,而我们以后将经常遇到化学反应。
That bond multiple of 72 is just a drag on returns -what's the point?
债券72倍的收益看起来像在拖后腿,为什么还要投资于债券呢
So the point is, this balance between energy thatyou could think of as say bond energies in chemical reactions, and entropy that you can think of in terms of disorder, how many different possible combinations or configurations of something wrong, will dictate where the equilibrium lies.
关键在于,这种能量与熵之间的平衡,确定了平衡的条件,在化学中能量涉及键能,而熵和无序有关,即有多少可能的不同组合或者形位,二者的平衡会告诉我们平衡态是什么样子。
So even though we see a nodal plane down the center, I just want to really point out that it's only when we have a nodal plane in the internuclear or the bond axis that we're calling that a pi orbital.
虽然在中间有个节面,我想要指出的是,只有节面在核间轴,或者键轴上时,我们才叫它π轨道。
So again, we can name these molecular orbitals and these we're going to call also to point out there is now a bond axis along this nodal plane, which is something we didn't see before when we were combining the s orbitals.
同样的,我们可以,命名这些分子轨道,这些轨道叫做-同样要指出的是,现在沿着键轴是一个节点面,这是我们讨论s轨道的时候,从没有看到过的。
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