• Let's look at the energetics of one of those electrons crashing into a hydrogen atom inside the gas tube.

    我们一起来考察一下,其中的一个电子的能量,在阴极射线管中,撞击到氢原子上。

    麻省理工公开课 - 固态化学导论课程节选

  • OK, then it says draw a single bond from each surrounding atom to the central atom, and subtract two valence electrons.

    后将中心原子与其相邻原子之间,连上单键,然后减掉2个价电子。

    麻省理工公开课 - 固态化学导论课程节选

  • So if I tell you that the energy for single hydrogen atom is negative 13 12 kilojoules per mole.

    如果我告诉大家单个氢原子的能量,是负的,1312,千焦每摩尔。

    麻省理工公开课 - 化学原理课程节选

  • z So, this is what we find the actual z effective is for an electron in the helium atom.

    所以这就是我们得到了实际有效的,对于一个氦原子的电子。

    麻省理工公开课 - 化学原理课程节选

  • We are going to now go into the atom and try to understand the scientific basis for this observed behavior.

    我们现在要讲讲原子,并试着去理解这个观察行为,的科学原理。

    麻省理工公开课 - 固态化学导论课程节选

  • Sometimes we have a very electronegative atom that's going to take more of its equal share of electron density.

    有时候我们会有一个电负性很高的原子,它将会获取更多的共用电子密度。

    麻省理工公开课 - 化学原理课程节选

  • Right, we had one from each atom, so that means we need a total of two in our molecular orbital.

    对吧,每个原子有一个电子,这意味着在分子轨道里我们一共需要两个电子。

    麻省理工公开课 - 化学原理课程节选

  • So why don't you tell me what the formal charge should be on the sulfur atom of thionyl chloride?

    那么请大家来告诉我亚硫酰氯中,的硫原子应该有多少形式电荷?

    麻省理工公开课 - 化学原理课程节选

  • One of the main difference is is that when you're talking about multi-electron orbitals, they're actually smaller than the corresponding orbital for the hydrogen atom.

    其中最主要的区别之一,是当你讨论多电子轨道时,它们实际上,要比对应的氢原子轨道,要小一些。

    麻省理工公开课 - 化学原理课程节选

  • Because what it tells is that we can figure out exactly what the radius of an electron and a nucleus are in a hydrogen atom.

    我们可以,准确的算出,氢原子中,电子。

    麻省理工公开课 - 化学原理课程节选

  • Gas phase single atom. So we don't have to deal with work function or any kind of energies associated with some condensed form of matter.

    气相的单原子,所以我们不需要再,处理功函数的问题,以及和凝聚态相关的能量问题。

    麻省理工公开课 - 固态化学导论课程节选

  • All right. So, let's pick up where we left off, first of all we're still on the hydrogen atom from Monday.

    好,让我们从上次停下的地方讲起,我们还要讲周一讲的氢原子。

    麻省理工公开课 - 化学原理课程节选

  • When it breaks this bond, that chlorine atom, a free chlorine atom comes down and reacts, this is ozone, with the ozone in the upper atmosphere.

    当它打破这个化学键,氯原子,一个自由的氯原子下来,和在大气层的上方的臭氧反应,这就是臭氧,在大气上层有臭氧。

    麻省理工公开课 - 固态化学导论课程节选

  • And today we'll finish that discussion, and, of course, point out actually the failure of classical mechanics to appropriately describe what's going on in an atom.

    结束这部分的讨论,当然的,要指出经典力学,在描述原子内部,情况时是失败的。

    麻省理工公开课 - 化学原理课程节选

  • a0 This is equal to a sub nought for a hydrogen atom, and we remember that that's just our Bohr radius, which is . 5 2 9 angstroms.

    它等于,我们记得,这就是波尔半径,也就是0,529埃,实际上。

    麻省理工公开课 - 化学原理课程节选

  • So it's trigonal because we have these three atoms that are bound to the central atom here, and if you picture it, it's actually shaped like a pyramid.

    这里三角形是因为,我们有3个原子核中心原子成键,如果你画它,它就是金字塔形的。

    麻省理工公开课 - 化学原理课程节选

  • So a plus two ion means that we're removing two electrons from the atom and the electrons that we're going to remove are always going to be the highest energy electrons.

    一个2价正离子,我们要移除的两个电子,我们要移除的两个电子,将会是,最高能量的电子。

    麻省理工公开课 - 化学原理课程节选

  • We're going to be looking at the solutions to the Schrodinger equation for a hydrogen atom, and specifically we'll be looking at the binding energy of the electron to the nucleus.

    我们将研究下氢原子薛定谔方程的解,特别是电子和核子的结合能,我们将研究这部分。

    麻省理工公开课 - 化学原理课程节选

  • So in terms of the first step of skeletal structure, this is actually going to be easier because we don't have a central atom, we just have carbon and nitrogen here.

    对于第一步画出骨架,其实比刚才更容易,因为我们没有一个中心原子,我们这里只有碳和氮两个原子。

    麻省理工公开课 - 化学原理课程节选

  • In terms of where different atoms are in a molecule, if you have a hydrogen atom or a fluorine atom, you can pretty much guarantee they're always going to be terminal atoms.

    对于不同原子在分子中的位置,如果你有一个氢原子或者一个氟原子,那你基本可以保证,它们总是最末端的原子。

    麻省理工公开课 - 化学原理课程节选

  • Because here what we have is some atom that we're studying, in the case, it's going to be a gas, and we hit it with a photon that has some incident energy.

    因为这里我们要研究的是一些原子,在这种情况下,一般是气态的,然后我们令一个,具有一定初始能量的光子打上去。

    麻省理工公开课 - 化学原理课程节选

  • Step three in our Lewis structure rules is to figure out how many electrons we would need in order for every single atom in our molecule to have a full valence shell.

    路易斯结构规则的第三步是,找出让分子中每个原子的价壳层,都排满应该需要多少个价电子。

    麻省理工公开课 - 化学原理课程节选

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