So what we'll have here is a trigonal planar case, and you can see that we only have three electrons that are set for bonding, so we'll add three hydrogens, and for b h 3, we'll get a stable structure here.
让电子劲量远离的时候,不用考虑它,这个例子是平面三角形,你可以看到,只有3个电子可以成键。
I got my first bachelor's in Graphic Design
我的第一个学士学位是平面设计,
And so it has what? In contrast to the sigma, it has a nodal plane containing both nuclei.
这是什么,和sigma相反,它是包覆在核上的平面电子云,有一个界面。
And when we look at this, it's actually split by what's called a nodal plane, which is pointed out in light orange here on this picture, but what we just mean is that there is this whole plane that separates the two lobes where there is absolutely no electron density.
我们来看这里,实际上它被一个节面分开,在这图里用淡黄色表示,这意味着这个分开,两个叶瓣的平面上,是完全没有电子密度的。
You go back to the same x-y plane; here is some vector A.
回到刚才的 x-y 平面上,这是某个矢量 A
And the nodal plane's going to be in the x z plane, or again, anywhere where phi is going to be equal to 0, that takes us to the x z plane.
节面是xz平面,又或者说是phi等于0的地方,这就是xz面。
So, the wave function at all of these points in this plane is equal to zero, so therefore, also the wave function squared is going to be equal to zero.
因此这里的,波函数平方也等于零,如果我们说在这整个平面上,任何地方找到一个p电子的概率都是零。
Our picture now is going to be some particle that's traveling in the x-y plane.
我们现在的情景是在 x-y 平面内,运动的质点
So again, if we think about that shape of that carbon atom, it's going to be trigonal planar, 120° it's going to have bond angles of 120 degrees, because we have this set up of having three hybrid orbitals.
如果我们考虑碳原子的形状,它是平面三角形,键角是,因为我们有这三个杂化轨道。
Um-hmm. So, it's going to be the y z nodal plane, or in other words, we can say it's any place where phi is equal to 90 degrees.
嗯,是yz平面,换句话说,是在phi等于90度的面。
But in sigma orbitals, you have no nodal planes along the bond axis, so if we had a nodal plane here, we'd see an area where the wave function was equal to zero.
但在sigma轨道里,沿着轴向是没有节点平面的,如果我们有个节点,我们就会看到某个地方波函数等于0。
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