And the way that we'll do this is starting with talking about the discovery of the electron and the nucleus here.

在这之后,我们就可以通过,经典力学来描述一个原子。

麻省理工公开课 - 化学原理课程节选

So, what we can do is try using the classical description of the atom and see where this takes us.

用经典力学描述原子看看怎么样,我们要考虑的是一个,带正电的粒子和。

麻省理工公开课 - 化学原理课程节选

You'd learn about statistical mechanics, and how the atomistic concepts rationalize thermodynamics.

你会学到在统计力学中，是如何用原子论的概念,阐释热力学的。

麻省理工公开课 - 热力学与动力学课程节选

And today we'll finish that discussion, and, of course, point out actually the failure of classical mechanics to appropriately describe what's going on in an atom.

结束这部分的讨论，当然的，要指出经典力学,在描述原子内部,情况时是失败的。

麻省理工公开课 - 化学原理课程节选

And, as I mentioned, we left off and as we started back here to describe the atom and how the atom holds together the nucleus and the electron using classical mechanics.

我之前提及过，我们上次,讲到应用经典力学如何描述,一个原子以及原子如何把质子,和电子束缚在一起，今天我们要。

麻省理工公开课 - 化学原理课程节选

So, let's see how some of this works, and hopefully your counterparts from 100 years ago would also be able to think about how this works, even if they don't have the quantum mechanics behind the individual electron configurations for atoms.

那么，下面让我们来看一下它是怎么用的，希望一百年前想你们一样的同学,也能够弄懂它为什么能用，尽管他们没有量子力学,不知道原子的电子排布。

麻省理工公开课 - 化学原理课程节选

And they had this feeling because there had just been this huge boon of discovery, of scientific advances that included Newtonian mechanics, it included Dalton's atomic theory of matter, also thermodynamics and classical electromagnetism.

他们会有这样的感觉,是因为他们刚，经历科学上的,大繁荣期，包括牛顿力学,道尔顿物质原子理论，热力学和电磁学,都取得了巨大进展。

麻省理工公开课 - 化学原理课程节选

So, I said I'd tell you a little bit more about where this Bohr radius came from, and it came from a model of the atom that pre-dated quantum mechanics, and Neils Bohr is who came up with the idea of the Bohr radius, and here is hanging out with Einstein, he had pretty good company that he kept.

我要告诉你们,波尔半径是从哪里来的,它起源于前量子力学时代的，原子模型,尼尔斯，玻尔提出了，波尔半径的概念,这是他和爱因斯坦在一起，他们是好朋友，当我们讨论这个原子模型时你们要记住的是，在1911年。

麻省理工公开课 - 化学原理课程节选

So, I will point out, in terms of MO theory, because it rigorously does take into account quantum mechanics, it starts to become complicated once we go beyond diatomic molecules.

我要指出的是，对于MO理论，以为它严格的遵守量子力学，所以一旦超过双原子分子,就变得十分复杂了。

麻省理工公开课 - 化学原理课程节选