And the reason is, and this will come up on the problems and a lot of students end up using this equation, which is why I want to head it off and mention it ahead of time, we can't use an equation because this equation is very specific for light.

原因是，很多同学在解题时,都会用这个方程，所以我要,事先提醒你们一下,我们不能用这个方程，因为它只对光是用。

麻省理工公开课 - 化学原理课程节选

So, what we say here is we need to take a step back here and come up with an approximation that's going to allow us to think about using the Schrodinger equation when we're not just talking about hydrogen or one electron, but when we have these multi-electron atoms.

所有我们这里要说的是,我们需要退回一步,做一个近似,那样可以使我们用,薛定谔方程来考虑,让我们不是仅仅在讨论氢原子或者,一个电子的时候，而是多个电子的原子。

麻省理工公开课 - 化学原理课程节选

So, we just want to appreciate that what we'll be using in this class is, in fact, the solutions to the Schrodinger equation, and just so you can be fully thankful for not having to necessarily solve these as we jump into the solutions and just knowing that they're out there and you'll get to solve it at some point, hopefully, in your careers.

所以，我们仅仅想要鉴别,将会在这门课中用到的，事实上就是薛定谔方程的解，而且你们可以非常欣慰,因为你们没有必要去,解这些方程而是直接用它们的解,并且知道这些解出自那里,希望你们在学习生涯中。

麻省理工公开课 - 化学原理课程节选

So, we can do that by using this equation, which is for s orbitals is going to be equal to dr 4 pi r squared times the wave function squared, d r.

用这个方程,对于s轨道，径向概率分布,4πr的平方,乘以波函数的平方,这很容易理解。

麻省理工公开课 - 化学原理课程节选

So we know that we can relate to z effective to the actual energy level of each of those orbitals, and we can do that using this equation here where it's negative z effective squared r h over n squared, we're going to see that again and again.

我们知道我们可以将有效电荷量与,每个轨道的实际能级联系起来，我们可以使用方程去解它,乘以RH除以n的平方,它等于负的有效电荷量的平方,我们将会一次又一次的看到它。

麻省理工公开课 - 化学原理课程节选